10464-U
Carbopack™ Adsorbent
matrix Carbopack™ Y, 120-400 mesh, bottle of 50 g
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product line
Carbopack™
form
granular
packaging
bottle of 50 g
technique(s)
LPLC: suitable
surface area
~24 m2/g
matrix
Carbopack™ Y
matrix active group
carbon
particle size
120-400 mesh
pore size
~0 cm3/g macroporosity
~0 cm3/g mesoporosity
~0 cm3/g microporosity
~0 Å pore diameter
density
~0.38 g/mL (free fall density)
separation technique
reversed phase
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General description
Carbotrap®/Carbopack™ adsorbent can withstand high bake-out temperature without losing the mechanical and chemical integrity. It has a high affinity for isoprene and does not retain significant amounts of water. Furthermore it has a tendency to pulverize if it is packed too tightly. Carbotrap®/Carbopack™ adsorbent was used to quantitatively determine trace amounts of volatile organic compounds (VOCs) in air. It was also used for designing sampling protocols on the basis of its retention volume of the gaseous organic compounds of interest.
A graphitized carbon black (GCB) can be non-porous or porous. The graphitization process results in a highly pure surface with great adsorption and desorption (if required) properties. Surface interactions depend solely on dispersion (London) forces. These particles are:
Generally, GCB adsorbents offer weaker relative adsorptive strength compared to carbon molecular sieve (CMS) adsorbents, and similar relative adsorptive strength compared to spherical graphitized polymer carbon (SGPC) adsorbents. Our Carbopack products are a type of GCB adsorbent.
For more information about any of our specialty carbon adsorbents, please visit sigma-aldrich.com/carbon
- Granular
- Friable
- Used for molecules with an analyte size relative to C3-C20+ n-alkanes
- Hydrophobic (can be used in high humidity environments)
Generally, GCB adsorbents offer weaker relative adsorptive strength compared to carbon molecular sieve (CMS) adsorbents, and similar relative adsorptive strength compared to spherical graphitized polymer carbon (SGPC) adsorbents. Our Carbopack products are a type of GCB adsorbent.
- Particles are 40 mesh and smaller
- Use 40/60 mesh to prevent channeling (if observed with a 20/40 mesh Carbotrap® adsorbent)
- Use smaller mesh (60/80, 80/100, etc.) for all other applications
- Use the smallest particle size available as long as the application can handle the pressure drop
For more information about any of our specialty carbon adsorbents, please visit sigma-aldrich.com/carbon
Application
Carbopack™ Y was used for determination of contamination caused by pesticides like alachlor, atrazine, captan, formothion, lindane and phosalone in atmospheric samples. Carbopack™ Y was modified with mono-molecular layer of heptakis-(2,3,6-tri-O-methyl)-ß-cyclodextrin and was used in gas chromatography to study the effect of size and spatial structure of adsorbate molecules on adsorption of organic vapours.
Legal Information
Carbopack is a trademark of Merck KGaA, Darmstadt, Germany
Carbotrap is a registered trademark of Merck KGaA, Darmstadt, Germany
WGK
nwg
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Regulatory Information
新产品
Certificates of Analysis (COA)
Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.
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Adsorption of organic vapors on the Carbopack Y carbon adsorbent modified with heptakis-(2, 3, 6-tri-O-methyl)-?-cyclodextrin.
Kudryashov SY, et al.
Russian Journal of Physical Chemistry A, 84 (3), 495-502 (2010)
Gas phase retention volume behavior of organic compounds on Carbotrap graphitized carbon.
Pankow JF.
Journal of Chromatography A, 547, 488-493 (1991)
Comparison of Tenax TA and Carbotrap for sampling and analysis of volatile organic compounds in air.
Rothweiler H, et al.
Atmospheric Environment, 25 (2), 231-235 (1991)
Li-Ming Yuan et al.
Analytical chemistry, 78(18), 6384-6390 (2006-09-15)
Single-walled carbon nanotubes (SWNTs) have high surface area, high adsorption ability, and nanoscale interactions. In this study, capillary columns including SWNTs, ionic liquid (IL), and IL + SWNTs for GC were prepared. The separation results showed that SWNTs possessed a
S A Heberle et al.
Analytical chemistry, 72(4), 840-845 (2000-03-04)
This paper describes a procedure for simultaneous enrichment, separation, and quantification of acetanilide herbicides and their major ionic oxanilic acid (OXA) and ethanesulfonic acid (ESA) metabolites in groundwater and surface water using Carbopack B as a solid-phase extraction (SPE) material.
Articles
Synthetic CMS carbons offer tailored adsorbents for specific applications.
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