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Key Documents

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Safety Information

254312

Sigma-Aldrich

Titanium(IV) chloride

≥99.995% trace metals basis

Synonym(s):

TTC, Titanium tetrachloride

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Select a Size

100 MG
CN¥529.62
500 MG
CN¥1,878.18
1 G
CN¥2,610.59
5 G
CN¥10,455.30

CN¥529.62

Available to ship onApril 23, 2025Details

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100 MG
CN¥529.62
500 MG
CN¥1,878.18
1 G
CN¥2,610.59
5 G
CN¥10,455.30

About This Item

Linear Formula:
TiCl4
CAS Number:
7550-45-0
Molecular Weight:
189.68
EC Number:
231-441-9
MDL number:
MFCD00011267
UNSPSC Code:
12352300
PubChem Substance ID:
329752736
NACRES:
NA.55
form:
liquid
liquid

CN¥529.62

Available to ship onApril 23, 2025Details

Request a Bulk Order

vapor pressure

50 mmHg ( 55 °C)
9.6 mmHg ( 20 °C)

Quality Level

100

Assay

≥99.995% trace metals basis

form

liquid
liquid

reaction suitability

reagent type: catalyst
core: titanium

bp

135-136 °C (lit.)
136.4 °C

mp

−25 °C (lit.)

density

1.73 g/mL at 20 °C (lit.)

SMILES string

Cl[Ti](Cl)(Cl)Cl

InChI

1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4

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Show Differences

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53919U53918U53910U
Ascentis® Express RP-Amide, 2.7 μm HPLC Column 2.7 μm particle size, L × I.D. 15 cm × 2.1 mm

53914U

Ascentis® Express RP-Amide, 2.7 μm HPLC Column

Ascentis® Express RP-Amide, 2.7 μm HPLC Column 2.7 μm particle size, L × I.D. 15 cm × 3 mm

53919U

Ascentis® Express RP-Amide, 2.7 μm HPLC Column

Ascentis® Express RP-Amide, 2.7 μm HPLC Column 2.7 μm particle size, L × I.D. 10 cm × 3 mm

53918U

Ascentis® Express RP-Amide, 2.7 μm HPLC Column

Ascentis® Express RP-Amide, 2.7 μm HPLC Column 2.7 μm particle size, L × I.D. 3 cm × 2.1 mm

53910U

Ascentis® Express RP-Amide, 2.7 μm HPLC Column

particle size

2.7 μm

particle size

2.7 μm

particle size

2.7 μm

particle size

2.7 μm

matrix active group

amide, alkyl phase

matrix active group

amide, alkyl phase

matrix active group

amide, alkyl phase

matrix active group

amide, alkyl phase

matrix

Fused-Core® particle platform, superficially porous particle

matrix

Fused-Core® particle platform, superficially porous particle

matrix

Fused-Core® particle platform, superficially porous particle

matrix

Fused-Core® particle platform, superficially porous particle

technique(s)

HPLC: suitable, UHPLC-MS: suitable, LC/MS: suitable, UHPLC: suitable

technique(s)

HPLC: suitable, LC/MS: suitable, UHPLC-MS: suitable, UHPLC: suitable

technique(s)

HPLC: suitable, LC/MS: suitable, UHPLC-MS: suitable, UHPLC: suitable

technique(s)

HPLC: suitable, LC/MS: suitable, UHPLC-MS: suitable, UHPLC: suitable

pore size

90 Å

pore size

90 Å

pore size

90 Å

pore size

90 Å

General description

Titanium(IV) chloride participates in the Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone.[1] Neutral solutions of TiCl4 having a pH in the range of 2.5 to 6.0 (prepared by the addition of magnesium oxide as a base) are used to synthesize nanosized titanium dioxide.[2]

Application

Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines.[3]
Promotes a highly selective aldol reaction of (S)-2-benzyloxy-3-pentanone in THF or DME.[4]
Titanium(IV) chloride has been used in the synthesis of anatase TiO2 structures with macropores (250nm in diameter) and mesoscale pores (50nm in diameter).[5]

Pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

Signal Word

Danger

Hazard Statements

H314,H330,H335

Hazard Classifications

Acute Tox. 1 Inhalation - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

EUH014

Storage Class Code

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

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    Certificates of Analysis (COA)

    Lot/Batch Number
    MKCW2181
    MKCT2495
    MKCS0810
    MKCS8024
    MKCR9248

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    Find documentation for the products that you have recently purchased in the Document Library.

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    A Review of Mesoporous TiO2 Thin Films
    Wang J, et al.
    Material Matters, 7(2) null
    Victor Rodríguez-Cisterna et al.
    The Journal of organic chemistry, 72(17), 6631-6633 (2007-07-20)
    Stereoselectivity of TiCl4-mediated aldol reactions from (S)-2-benzyloxy-3-pentanone is dramatically improved when the reaction is carried out in the presence of 1.1 equiv of tetrahydrofuran (THF) or 1,2-dimethoxyethane (DME). The resultant 2,4-syn-4,5-syn adducts are then obtained in diastereomeric ratios up to
    Titanium(IV) chloride and the amine-promoted baylis-hillman reaction
    Shi et al.
    Organic letters, 2(23), 3755-3755 (2000-11-14)
    Precipitation of nanosized titanium dioxide from aqueous titanium (IV) chloride solutions by neutralization with MgO.
    Li Y and Demopoulos GP.
    Hydrometallurgy, 90(1), 26-33 (2008)
    Bratindranath Mukherjee et al.
    Nanoscale, 5(1), 269-274 (2012-11-20)
    The surface treatment of an anodized TiO(2) nanotube (T_NT) is very desirable for enhancing its photoelectrochemical properties and often is a prerequisite to deposition of any overlying layer for photoactivity efficiency improvement. This study provides a comparative analysis of the
    View All Related Papers

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