208930
Tin(IV) chloride
98%
Synonym(s):
Stannic chloride fuming
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About This Item
Recommended Products
vapor density
9 (vs air)
Quality Level
vapor pressure
10 mmHg ( 10 °C)
18.6 mmHg ( 20 °C)
20 mmHg ( 22 °C)
Assay
98%
form
liquid
reaction suitability
core: tin
reagent type: Lewis acid
reagent type: catalyst
bp
114 °C (lit.)
mp
−33 °C (lit.)
density
2.226 g/mL at 25 °C (lit.)
SMILES string
Cl[Sn](Cl)(Cl)Cl
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Related Categories
1 of 4
This Item | 259950 | B12695 | 801809 |
|---|---|---|---|
| assay 99% | assay 98.0-100.5%, 99% | assay ≥99% | assay ≥99.0% (GC) |
| solubility 0.46 g/L at 30 °C (Decomposes in contact with water) | solubility - | solubility - | solubility 460 mg/L |
| Quality Level 200 | Quality Level 200 | Quality Level 200 | Quality Level 200 |
| refractive index n20/D 1.538 (lit.) | refractive index n20/D 1.553 (lit.) | refractive index n20/D 1.553 (lit.) | refractive index - |
| bp 177-181 °C (lit.) | bp 198 °C (lit.) | bp 198 °C (lit.) | bp 179.3 °C/1013 hPa |
| mp −43 °C (lit.) | mp −1 °C (lit.) | mp −1 °C (lit.) | mp -39 °C |
General description
Application
- Cyclization of trans β-monocyclohomofarnesic acid to form norambreinolide.[2]
- Formation of C-glycosides of aromatic compounds such as thiophene, naphthalene and phloroglucinol trimethyl ether.[3]
- Formal [4+2] cycloaddition of 3-ethoxycyclobutanones and allyltrialkylsilanes to form 3-ethoxy-5-[(trialkylsilyl)methyl]cyclohexan-1-ones.[4]
- Diastereoselective reaction of δ-alkoxyallylstannanes with aldehydes to form 1,5-diol derivatives.[5]
Other applications of SnCl4:
- The SnCl4-2,6-dialkoxyphenols complexes can catalyze cyclization of poylenes, such as 4-(homogeranyl)toluene to form trans-fused tricyclic compound.[6]
- SnCl4 can act as a promoter during the reaction of ortho-aminobenzonitriles with β-ketoesters and β-enaminonitriles to form 4-aminoquinolines and 4-aminopyridines, respectively.[7]
- SnCl4-silver perchlorate forms an effective catalytic system for the stereoselective of glycosylation 1-O-acetyl glucose.[8]
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
Regulatory Information
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