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Merck
CN

T82600

Triphenylene

98%

Synonym(s):

9,10-Benzophenanthrene

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About This Item

Empirical Formula (Hill Notation):
C18H12
CAS Number:
Molecular Weight:
228.29
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
205-922-9
Beilstein/REAXYS Number:
1342908
MDL number:
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Product Name

Triphenylene, 98%

InChI key

SLGBZMMZGDRARJ-UHFFFAOYSA-N

InChI

1S/C18H12/c1-2-8-14-13(7-1)15-9-3-4-11-17(15)18-12-6-5-10-16(14)18/h1-12H

SMILES string

c1ccc2c(c1)c3ccccc3c4ccccc24

assay

98%

bp

438 °C (lit.)

mp

195-198 °C (lit.)

fluorescence

λex 265 nm; λem 372 nm in cyclohexane

Quality Level

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pictograms

CorrosionEnvironment

signalword

Danger

hcodes

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1

Storage Class

11 - Combustible Solids

wgk

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Gloves


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  1. Which document(s) contains shelf-life or expiration date information for a given product?

    If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.

  2. How do I get lot-specific information or a Certificate of Analysis?

    The lot specific COA document can be found by entering the lot number above under the "Documents" section.

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  4. What is the Department of Transportation shipping information for this product?

    Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product. 

  5. What solvents can be used to dissolve Product T82600, Triphenylene?

    According to the chemicals encyclopedia published by the Royal Society of Chemistry, triphenylene is expected to be soluble in chloroform or ethanol.

  6. Is Product T82600, Triphenylene, fluorescently active?

    Yes. Triphenylene emits a blue fluorescence upon UV irradiation.

  7. How can Product T82600, Triphenylene, be used?

    Because of its stability towards hydrogenation, triphenylene has been used in optical and display devices.

  8. My question is not addressed here, how can I contact Technical Service for assistance?

    Ask a Scientist here.

Martin Kaller et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 16(21), 6326-6337 (2010-04-23)
The twisted lateral tetraalkyloxy ortho-terphenyl units in dibenzo[18]crown-6 ethers 1a-f were readily converted into the flat tetraalkyloxytriphenylene systems 2a-f by oxidative cyclization with FeCl(3) in nitromethane. Reactions of the latter with potassium salts gave complexes KX.2, which displayed mesomorphic properties.
Md Akhtarul Alam et al.
Journal of the American Chemical Society, 131(49), 17722-17723 (2009-12-10)
Triphenylene (TP) derivatives bearing appropriate paraffinic side chains with imidazolium ion-based ionic liquid (IL) pendants were unveiled to display a phase diagram with liquid crystalline (LC) mesophases of bicontinuous cubic (Cub(bi)) and hexagonal columnar (Col(h)) geometries. While their phase transition
Ozcan Kocyigit et al.
Journal of hazardous materials, 183(1-3), 334-340 (2010-08-10)
We presented the synthesis of a novel Schiff base and its complexation properties with some transition metal ions in this work. For this, the 2,3,4,6,7,10,11 hexahydroxytriphenylene (HHTP) as starting material was synthesized according to known procedure. Moreover, the 2-((2-chloroethylimino)methyl) phenol
Lucas A Haverkate et al.
The journal of physical chemistry. B, 116(43), 13098-13105 (2012-10-05)
Discotic liquid crystalline (DLC) charge transfer (CT) complexes, which combine visible light absorption with rapid charge transfer characteristics within the CT complex, can have a great potential for photovoltaic applications when they can be made to self-assemble in a bulk
Vandana Bhalla et al.
Dalton transactions (Cambridge, England : 2003), 41(37), 11413-11418 (2012-08-15)
The binding behavior of triphenylene based copper ensemble prepared in situ has been investigated toward various anions (F(-), Cl(-), Br(-), I(-), CH(3)COO(-), H(2)PO(4)(-), NO(3)(-), OH(-), ClO(4)(-), CN(-), CO(3)(-) and SO(4)(-)) by UV-vis and fluorescence spectroscopy. Among various anions tested, 1-Cu(2+)

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