All Photos(1)
Synonym(s):
Mesylate[(di(1-adamantyl)-n-butylphosphine)-2-(2′-amino-1,1′-biphenyl)]palladium(II), [(Di(1-adamantyl)-butylphosphine)-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate, cataCXium-A-Pd-G3
Empirical Formula (Hill Notation):
C37H52NO3PPdS
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![[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane](/deepweb/assets/sigmaaldrich/product/structures/825/986/4317978b-1256-4c82-ab74-6a6a3ef948b1/640/4317978b-1256-4c82-ab74-6a6a3ef948b1.png)
![[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)](/deepweb/assets/sigmaaldrich/product/structures/130/734/8846aa26-1858-458a-998d-8c306c13bf0f/640/8846aa26-1858-458a-998d-8c306c13bf0f.png)
form
solid
Quality Level
composition
~ 4 wt.% loading of catalyst
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
Application
cataCXium® A Pd G3 is a Buchwald third generation precatalyst that can be used in:
Learn more about ChemBeads products
For larger scale uses, product also available in powdered form (761435)
- Direct ortho-arylation of pyridinecarboxylic acids.
- Catalyzing Suzuki–Miyaura cross-coupling in the synthesis of 1-heteroaryl-3-azabicyclo[3.1.0]hexanes.
- Palladium-catalyzed carbonylative carboperfluoroalkylation of alkynes.
- Suzuki–Miyaura coupling reaction of geminal bis(boryl)cyclopropanes in the synthesis of various gem-disubstituted cyclopropanes.
Learn more about ChemBeads products
For larger scale uses, product also available in powdered form (761435)
Other Notes
High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads
Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation
ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand
Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation
ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand
Legal Information
cataCXium is a registered trademark of Umicore AG & Co. KG
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Description
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Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Carc. 1B Inhalation
WGK
WGK 3
Regulatory Information
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