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Ni(IPr*OMe)(phenyl acrylate)2

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Synonym(s):
Montgomery Ni catalyst
Empirical Formula (Hill Notation):
C87H72N2NiO6
CAS Number:
Molecular Weight:
1300.21
UNSPSC Code:
12352103
NACRES:
NA.22

form

powder

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

Application

Ni(IPr*OMe)(phenyl acrylate)2 is an NHC-Ni(0) precatalyst developed in the Montgomery lab used for a variety of synthetic transformations including reductive couplings of aldehydes and alkynes and N-arylation of amines.

related product

Product No.
Description
Pricing

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

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Alex J Nett et al.
ACS catalysis, 8(7), 6606-6611 (2018-08-07)
The synthesis and catalytic activity of several classes of NHC-Ni(0) pre-catalysts stabilized by electron-withdrawing alkenes are described. Variations in the structure of fumarate and acrylate ligands modulate the reactivity and stability of the NHC-Ni(0) pre-catalysts and lead to practical and

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Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

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