901426
Propargyl methacrylate
≥98.0%, contains 200 ppm MEHQ as inhibitor
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About This Item
Empirical Formula (Hill Notation):
C7H8O2
CAS Number:
Molecular Weight:
124.14
MDL number:
UNSPSC Code:
12162002
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Assay
≥98.0%
form
liquid
color
colorless to pale yellow
storage temp.
−20°C
InChI
1S/C7H8O2/c1-4-5-9-7(8)6(2)3/h1H,2,5H2,3H3
InChI key
PZAWASVJOPLHCJ-UHFFFAOYSA-N
General description
Propargyl methacrylate is a methacrylate-based monomer for use in the synthesis of alkyne-functionalized polymers and copolymers. The incorporation of alkynes allows for rapid post-polymerization modification through reactions, such as copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) or thiol-yne click reactions. These reactions are highly preferable for functionalization due their high efficiency and the ability to easily install the corresponding functionality (e.g., azides or thiols) onto the biomolecule or small molecule of interest.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
120.2 °F
Flash Point(C)
49 °C
Regulatory Information
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Self-assembling amphiphilic poly(propargyl methacrylate) grafted DNA copolymers into multi-strand helices
Meng Y F, et al.
Soft Matter, 11, 5610- 513 (2015)
Postfunctionalization of poly(propargyl methacrylate) using copper catalyzed 1,3-dipolar Huisgen cycloaddition: An easy route to electro-optic materials
Scarpaci A. et al.
Journal of Polymer Science: Part A, General Papers, 47, 5652- 560 (2009)
Clickable and Antifouling Platform of Poly[(propargyl methacrylate)-ran-(2-methacryloyloxyethyl phosphorylcholine)] for Biosensing Applications
Wiarachai O, et al.
Langmuir, 32 (4), 1184-1194 (2016)
Jincai Wang et al.
Journal of chromatography. A, 1628, 461481-461481 (2020-08-22)
A single-step copolymerization strategy was developed for the preparation of carbohydrate (glucose and maltose) functionalized monoliths using click reaction. Firstly, novel carbohydrate-functionalized methacrylate monomers were synthesized through Cu(I)-catalyzed 1,3-dipolar cycloaddition (alkyne-azide reaction) of terminal alkyne with azide of carbohydrate derivatives.
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