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About This Item
Empirical Formula (Hill Notation):
C8H13NO3
CAS Number:
Molecular Weight:
171.19
MDL number:
UNSPSC Code:
12352209
Recommended Products
Assay
≥98.0%
form
liquid
color
colorless to pale yellow
storage temp.
−20°C
InChI
1S/C8H13NO3/c1-4-6(10)9-7(5(2)3)8(11)12/h4-5,7H,1H2,2-3H3,(H,9,10)(H,11,12)
InChI key
UHWCAAMSQLMQKV-UHFFFAOYSA-N
General description
N-Acryloylvaline (AVAL) is an acrylamide-functionalized, amino acid-based monomer. N-Acryloyl derivatives of amino acids are of synthetic interest due to their chirality, ability to self-assemble into higher order structures, and their potential for interpolyelectrolyte stabilization. For example, when copolymerized with N,N-dimethylacrylamide (DMA) and N-isopropylacrylamide (NIPAM) block copolymers were shown to undergo a reversible pH and temperature-induced unimer-to-micelle transition. Once assembled, these micelles can be reversibly crosslinked above the critical micelle temperature via interpolyelectrolyte complexation of the anionic poly(AVAL) segments with cationic polymers.
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Regulatory Information
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New thermal-responsive polymers based on alanine and (meth)acryl amides.
Yu D, et al.
Polym. Chem., 5, 4561-4568 (2014)
Aqueous RAFT Synthesis of Micelle-Forming Amphiphilic Block Copolymers Containing N-Acryloylvaline. Dual Mode, Temperature/pH Responsiveness, and ?Locking? of Micelle Structure through Interpolyelectrolyte Complexation.
Lokitz BS, et al.
Macromolecules, 40(18), 6473-6480 (2007)
Stimuli-responsive ampholytic terpolymers of N-acryloyl-valine, acrylamide, and (3-acrylamidopropyl)trimethylammonium chloride: Synthesis, characterization, and solution properties.
Ezell RG et al.
Journal of Polymer Science Part A: Polymer Chemistry, 44(9), 3125-3139 (2006)
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