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Key Documents

Safety Information

809330

Sigma-Aldrich

Fe/ppm Pd for nitro group reductions

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5 MG
CN¥1,297.23
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Available to ship onApril 27, 2025Details

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5 MG
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About This Item

MDL number:
MFCD00011005
UNSPSC Code:
12161600
NACRES:
NA.22

CN¥1,297.23

List PriceCN¥1,729.63Save 25%

Available to ship onApril 27, 2025Details

Request a Bulk Order

form

solid

Quality Level

100

composition

FeCl2 (372870), 23.3-27.4 wt. %
MgCl2 (M8266), 15.3-18.8 wt. %
Pd (203939), <0.3 wt. %
THF (186562), 53.5-61.6 wt. %

reaction suitability

core: iron
reagent type: catalyst

storage temp.

2-8°C

SMILES string

[Fe](Cl)(Cl)Cl

InChI key

RBTARNINKXHZNM-UHFFFAOYSA-K

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H6278H7904SML1122
PS48 &#8805;98% (HPLC)

P0022

PS48

4-Hydroxytamoxifen &#8805;70% Z isomer (remainder primarily E-isomer)

H6278

4-Hydroxytamoxifen

(Z)-4-Hydroxytamoxifen &#8805;98% Z isomer

H7904

(Z)-4-Hydroxytamoxifen

BTB06584 &#8805;98% (HPLC)

SML1122

BTB06584

assay

≥98% (HPLC)

assay

≥98% (HPLC)

assay

≥98% (HPLC)

assay

≥98% (HPLC)

form

powder

form

powder

form

powder

form

powder

Quality Level

100

Quality Level

300

Quality Level

300

Quality Level

100

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

storage condition

protect from light

storage condition

desiccated, protect from light

storage condition

desiccated, protect from light

storage condition

-

solubility

DMSO: >20 mg/mL

solubility

methanol: 10 mg/mL, ethanol: 20 mg/mL (with heating)

solubility

methanol: 10 mg/mL, ethanol: 20 mg/mL (with heating)

solubility

DMSO: 20 mg/mL, clear

Application

When these nanoparticles (NPs) are used along with PEG-containing designer surfactants such as TPGS-750-M, a facile reduction of nitro compounds can be effected in water at room temperature. The transformation is highly chemoselective and tolerates a large variety of functional groups.

Caution

Handle under nitrogen and store under argon in refrigerator.

Other Notes

Safe and Selective Nitro Group Reductions Catalyzed by Sustainable and Recyclable Fe/ppm Pd Nanoparticles in Water at Room Temperature
Watch Professor Lipshutz talk about Fe/ppm Pd in this webinar:
From milligrams to kilograms: synthetic chemistry following nature′s lead

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902292

EvanPhos, ≥95%

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

EUH018,EUH019

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

1.4 °F

Flash Point(C)

-17 °C

Regulatory Information

危险化学品

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    When Does Organic Chemistry Follow Nature?s Lead and ?Make the Switch?.
    Lipshutz B H
    The Journal of Organic Chemistry, 82(6), 2806-2816 (2017)
    New surfactants for chemistry in water.
    Krause N
    Current opinion in green and sustainable chemistry., 7, 18-22 (2017)
    Switching from organic solvents to water at an industrial scale.
    Parmentier M, et al.
    Current opinion in green and sustainable chemistry., 7, 13-17 (2017)

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