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805386

Sigma-Aldrich

FK 209 Co(II) TFSI salt

Synonym(s):

Greatcell Solar®, Tris(2-(1H-pyrazol-1-yl)-4-tert-butylpyridine)cobalt(II) di[bis(trifluoromethane)sulfonimide]

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About This Item

Empirical Formula (Hill Notation):
C40H45CoF12N11O8S4
Molecular Weight:
1223.03
UNSPSC Code:
12352103
PubChem Substance ID:
329768934
NACRES:
NA.23

Assay

98%

Quality Level

100

form

powder

mp

207 °C

SMILES string

O=S([N-]S(=O)(C(F)(F)F)=O)(C(F)(F)F)=O.O=S([N-]S(=O)(C(F)(F)F)=O)(C(F)(F)F)=O.CC(C)(C)C1=CC(N2N=CC=C2)=NC=C1.CC(C)(C)C3=CC=NC(N4C=CC=N4)=C3.CC(C)(C)C5=CC=NC(N6C=CC=N6)=C5.[Co+2]

InChI

1S/3C12H15N3.2C2F6NO4S2.Co/c3*1-12(2,3)10-5-7-13-11(9-10)15-8-4-6-14-15;2*3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/h3*4-9H,1-3H3;;;/q;;;2*-1;+2

InChI key

CUSFJXUEEGOGPG-UHFFFAOYSA-N

Related Categories

Application

Use this cobalt complexes to increase photovoltages of liquid electrolyte cells substantially or to achieve ultrahigh performance with solid state photovoltaic devices.

Legal Information

Product of Greatcell Solar®
Greatcell Solar is a registered trademark of Greatcell Solar

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H317,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

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Sandra M Feldt et al.
Physical chemistry chemical physics : PCCP, 15(19), 7087-7097 (2013-04-05)
Regeneration and recombination kinetics was investigated for dye-sensitized solar cells (DSCs) using a series of different cobalt polypyridine redox couples, with redox potentials ranging between 0.34 and 1.20 V vs. NHE. Marcus theory was applied to explain the rate of
Teck Ming Koh et al.
ChemSusChem, 7(7), 1909-1914 (2014-05-23)
In this work, we report a new cobalt(III) complex, tris[2-(1H-pyrazol-1-yl)pyrimidine]cobalt(III) tris[bis(trifluoromethylsulfonyl)imide] (MY11), with deep redox potential (1.27 V vs NHE) as dopant for 2,2',7,7'-tetrakis-(N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorene (spiro-OMeTAD). This dopant possesses, to the best of our knowledge, the deepest redox potential among all
Julian Burschka et al.
Nature, 499(7458), 316-319 (2013-07-12)
Following pioneering work, solution-processable organic-inorganic hybrid perovskites-such as CH3NH3PbX3 (X = Cl, Br, I)-have attracted attention as light-harvesting materials for mesoscopic solar cells. So far, the perovskite pigment has been deposited in a single step onto mesoporous metal oxide films
Edoardo Mosconi et al.
Journal of the American Chemical Society, 134(47), 19438-19453 (2012-11-02)
We report a combined experimental and computational investigation to understand the nature of the interactions between cobalt redox mediators and TiO(2) surfaces sensitized by ruthenium and organic dyes, and their impact on the performance of the corresponding dye-sensitized solar cells

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