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Sigma-Aldrich

Lithium bis(oxalato)borate

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Synonym(s):
LiBOB, Lithium bis(ethanedioato)borate, Lithium bis(oxalate)borate
Linear Formula:
LiB(C2O4)2
CAS Number:
244761-29-3
Molecular Weight:
193.79
MDL number:
MFCD07776904
UNSPSC Code:
26111700
PubChem Substance ID:
329766649
NACRES:
NA.23

form

powder or crystals

Quality Level

100

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Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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mp

>300 °C (lit.)

application(s)

battery manufacturing

greener alternative category

Enabling,

SMILES string

[Li+].O=C1O[B-]2(OC1=O)OC(=O)C(=O)O2

InChI

1S/C4BO8.Li/c6-1-2(7)11-5(10-1)12-3(8)4(9)13-5;/q-1;+1

InChI key

NVQAYVUCVASGDK-UHFFFAOYSA-N

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General description

Lithium bis(oxalato)borate (LiBOB) is a class of electrolytic materials that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.
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Application

LiBOB is a novel boron based Li salt electrolyte material for Li ion batteries. It is environmentally friendly with good film forming property and high thermal stability and is compatible with a variety of anodes and metal oxide cathode.
LiBOB is a thermally stable electrolyte that can be used to protect graphite-based anode materials in lithium-ion batteries. It shows good electrochemical performance with a discharge capacity retention of ~ 83%.

Legal Information

Product of Albemarle US Inc

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Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H302,H317,H318

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Sens. 1A

WGK

WGK 1

Certificates of Analysis (COA)

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Snehashis Choudhury et al.
Nature communications, 10(1), 4398-4398 (2019-09-29)
Electrochemical cells based on alkali metal anodes are receiving intensive scientific interest as potentially transformative technology platforms for electrical energy storage. Chemical, morphological, mechanical and hydrodynamic instabilities at the metal anode produce uneven metal electrodeposition and poor anode reversibility, which, are among the many
Surface layer formed on silicon thin-film electrode in lithium bis (oxalato) borate-based electrolyte
Choi N, et al.
Journal of Power Sources, 172(1), 404-409 (2007)
On the electrochemical and thermal behavior of lithium bis (oxalato) borate (LiBOB) solutions
Larush-Asraf L, et al.
Journal of Power Sources, 174(2), 400-407 (2007)
Jenny Strehlau et al.
Analytical and bioanalytical chemistry, 409(26), 6123-6131 (2017-08-05)
A novel method based on liquid-liquid extraction with subsequent gas chromatography separation and mass spectrometric detection (GC-MS) for the quantification of organic carbonates in cell culture materials is presented. Method parameters including the choice of extraction solvent, of extraction method
Wengao Zhao et al.
ChemSusChem, 11(13), 2211-2220 (2018-05-03)
The long-term cycling performance, rate capability, and voltage stability of lithium (Li) metal batteries with LiNi0.76 Mn0.14 Co0.10 O2 (NMC76) cathodes is greatly enhanced by lithium bis(oxalato)borate (LiBOB) additive in the LiPF6 -based electrolyte. With 2 % LiBOB in the electrolyte
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