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Sigma-Aldrich

Magnesium monoperoxyphthalate hexahydrate

technical, ~80% (RT)

Synonym(s):

Magnesium bis(monoperoxyphthalate) hexahydrate, MMPP

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About This Item

Linear Formula:
(HO2CC6H4CO3)2Mg·6H2O
Molecular Weight:
494.64
EC Number:
279-013-0
MDL number:
MFCD00149614
UNSPSC Code:
12352002
PubChem Substance ID:
57652217
NACRES:
NA.22

grade

technical

Quality Level

200

Assay

~80% (RT)

form

powder

reaction suitability

reagent type: oxidant

mp

93 °C (dec.) (lit.)

SMILES string

O.O.O.O.O.O.OOC(=O)c1ccccc1C(=O)O[Mg]OC(=O)c2ccccc2C(=O)OO

InChI

1S/2C8H6O5.Mg.6H2O/c2*9-7(10)5-3-1-2-4-6(5)8(11)13-12;;;;;;;/h2*1-4,12H,(H,9,10);;6*1H2/q;;+2;;;;;;/p-2

InChI key

WWOYCMCZTZTIGU-UHFFFAOYSA-L

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General description

Magnesium monoperoxyphthalate hexahydrate is an organic peroxide used in many oxidation reactions. It exhibits non-deflagrating and non-shock-sensitive properties and also used as a surface disinfectant.

Application

Reagent for:
  • Trans-diaxial hydroxylation under bismuth(III) triflate catalyst
  • Oxidation rections under mild conditions
  • Epoxidation of unsaturated steroids
  • Synthesis of ring-B oxygenated steroids as anticancer agents

Other Notes

Versatile oxidant soluble in water and the lower alcohols.; Oxidations are carried out in homogenous solution (alcohol, aqueous alcohol) or in a two-phase system under PTC (chloroform-water)

Signal Word

Danger

Hazard Statements

H242,H314,H332

Hazard Classifications

Acute Tox. 4 Inhalation - Eye Dam. 1 - Org. Perox. E - Skin Corr. 1C

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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D. Enders et al.
Synlett, 725-725 (1990)
Novel organic peroxygen reagents for use in organic synthesis
Organic peroxygen chemistry, 1-19 (1993)
F. Fringuelli et al.
The Journal of Organic Chemistry, 57, 1198-1198 (1992)
Efficacy of three surface disinfectants against spores of Clostridium difficile ribotype 027
Horejsh D and Kampf G
International Journal of Hygiene and Environmental Health, 214(2), 172-174 (2011)
P. Brougham et al.
Synthesis, 1015-1015 (1987)

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