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Sigma-Aldrich

Benz[b]anthracene

sublimed grade, 99.99% trace metals basis

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Synonym(s):
2,3-Benzanthracene, Naphthacene, Tetracene
Empirical Formula (Hill Notation):
C18H12
CAS Number:
92-24-0
Molecular Weight:
228.29
Beilstein:
1909299
EC Number:
202-138-9
MDL number:
MFCD00003702
UNSPSC Code:
12352103
PubChem Substance ID:
329761252
NACRES:
NA.23

grade

sublimed grade

Quality Level

100

Assay

99.99% trace metals basis

form

powder

mp

>300 °C (lit.)

λmax

277 nm

fluorescence

λem 481, 514 nm in dichloromethane-d2

Orbital energy

HOMO 5.4 eV 
LUMO 2.7 eV 

OPV Device Performance

ITO/PEDOT:PSS/tetracene/C60/BCP/Al

  • Short-circuit current density (Jsc): 7 mA/cm2
  • Open-circuit voltage (Voc): 0.58 V
  • Fill Factor (FF): 0.57
  • Power Conversion Efficiency (PCE): 2.3 %

semiconductor properties

P-type (mobility=0.4 cm2/V·s)

SMILES string

c1ccc2cc3cc4ccccc4cc3cc2c1

InChI

1S/C18H12/c1-2-6-14-10-18-12-16-8-4-3-7-15(16)11-17(18)9-13(14)5-1/h1-12H

InChI key

IFLREYGFSNHWGE-UHFFFAOYSA-N

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General description

Benz[b]anthracene is a fused polycyclic aromatic compound with an electron field-effect mobility of about 10 cm2 /Vs
Benz[b]anthracene is an ethylnylated acene that is a conducting polymer, which can be used as a donor material. It has a high photoluminescence and quantum yield that makes it a promising candidate in the development of single crystal electronic material.

Application

Benz[b]anthracene can be used in a wide range of organic electronics based devices, which include organic light emitting diodes (OLEDs), solar cells, organic photovoltaics (OPVs), thin film transistors (TFTs), and other single crystal based organic semiconductors.
p-Type organic conductor and OLED dopant. Sublimed grade for organic electronic device applications. Suitable for organic semiconductor lasers.

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Trap healing and ultralow-noise Hall effect at the surface of organic semiconductors.
Lee B, et al.
Testing, 12(12), 1125-1125 (2013)
25th Anniversary Article: Key Points for High-Mobility Organic Field-Effect Transistors.
Dong H, et al.
Advanced Materials, 25(43), 6158-6183 (2013)
Singlet exciton fission in nanostructured organic solar cells.
Jadhav PJ, et al.
Nano Letters, 11(4), 1495-1498 (2011)
Tetracene derivatives as potential red emitters for organic LEDs.
Odom SA, et al.
Organic Letters, 5(23), 4245-4248 (2003)
Electronic functionalization of the surface of organic semiconductors with self-assembled monolayers.
Calhoun MF, et al.
Testing, 7(1), 84-84 (2008)
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