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663905

Sigma-Aldrich

N,N′-Diphenyl-3,4,9,10-perylenedicarboximide

98%

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Synonym(s):
PTCDI-Ph
Empirical Formula (Hill Notation):
C36H18N2O4
CAS Number:
128-65-4
Molecular Weight:
542.54
EC Number:
204-902-7
MDL number:
MFCD00151605
UNSPSC Code:
12352103
PubChem Substance ID:
24884667
NACRES:
NA.23

Assay

98%

form

solid

mp

>300 °C

λmax

527 nm

fluorescence

λem ≤534 nm in chloroform

semiconductor properties

N-type (mobility=10−5 cm2/V·s)

SMILES string

O=C1N(c2ccccc2)C(=O)c3ccc4c5ccc6C(=O)N(c7ccccc7)C(=O)c8ccc(c9ccc1c3c49)c5c68

InChI

1S/C36H18N2O4/c39-33-25-15-11-21-23-13-17-27-32-28(36(42)38(35(27)41)20-9-5-2-6-10-20)18-14-24(30(23)32)22-12-16-26(31(25)29(21)22)34(40)37(33)19-7-3-1-4-8-19/h1-18H

InChI key

OGEZSLXPCKHGKO-UHFFFAOYSA-N

General description

N,N′-Diphenyl-3,4,9,10-perylenedicarboximide (PTCDI-Ph) is an asphaltene based conducting polymer that has an archipelago model. It is a perylene diimide derivative that has a high electron affinity and shows good chemical stability. It can be used as an active layer in the development of organic electronic devices.

Application

PTCDI-Ph is a conjugating polymer that forms an ultrathin film that can be used in the fabrication of organic field effect transistors (OFETs) for nitrogen dioxide sensor based applications.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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High performance nitrogen dioxide sensor based on organic field-effect transistor utilizing ultrathin CuPc/PTCDI-C8 heterojunction.
Fan H, et al.
Synthetic Metals, 211(9), 161-166 (2016)
The influence of CO2 on the structure of confined asphaltenes in calcite nanopores.
Mohammed S and Gadikota G
Fuel: The Science and Technology of Fuel and Energy, 236, 769-777 (2019)
Response enhancement mechanism of NO2 gas sensing in ultrathin pentacene field-effect transistors.
Mirza M, et al.
Organic Electronics, 24(9), 96-100 (2015)
Electronic structure of the conduction band of the interface region of ultrathin films of substituted perylenedicarboximides and the germanium oxide surface.
Komolov AS, et al.
Physics of the Solid State, 58(9), 1901-1905 (2016)
Heteroepitaxy growth high performance films of perylene diimide derivatives.
Huang L, et al.
Organic Electronics, 11(2), 195-201 (2010)

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Polymer Semiconductors for Intrinsically Stretchable Organic Transistors

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Soluble Pentacene Precursors

Fabrication procedure of organic field effect transistor device using a soluble pentacene precursor.

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