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Assay
96%
refractive index
n20/D 1.46 (lit.)
bp
90 °C/20 mmHg (lit.)
density
0.983 g/mL at 25 °C (lit.)
SMILES string
C[Si](C)(C)N1CCCC1=O
InChI
1S/C7H15NOSi/c1-10(2,3)8-6-4-5-7(8)9/h4-6H2,1-3H3
InChI key
LUBVCBITQHEVCJ-UHFFFAOYSA-N
General description
1-(Trimethylsilyl)-2-pyrrolidinone has been prepared by refluxing a mixture of 2-pyrrolidinone, triethylamine and trimethylchlorosilane in benzene. It undergoes sulfenylation with phenyl disulfide to form the corresponding bissulfide as the major product.
Application
1-(Trimethylsilyl)-2-pyrrolidinone may be used for the preparation of 1-(diphenylphosphonio)pyrrolidin-2-one and 1-(1-adamantylcarbonyl)-2-pyrrolidinone.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
WGK
WGK 3
Flash Point(F)
closed cup
Flash Point(C)
closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
新产品
Certificates of Analysis (COA)
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Find documentation for the products that you have recently purchased in the Document Library.
Synthesis and antiviral activity evaluation of some new aminoadamantane derivatives. 2.
Journal of Medicinal Chemistry, 39(17), 3307-3318 (1996)
Sulfenylation and sulfinylation of lactams and imino ethers.
The Journal of Organic Chemistry, 43(7), 1379-1382 (1978)
Synthesis, conformational characteristics and anti-influenza virus A activity of some 2-adamantylsubstituted azacycles.
Bioorganic Chemistry, 34(5), 248-273 (2006)
Efficient method for the preparation of carboxylic acid alkyl esters or alkyl phenyl ethers by a new-type of oxidation-reduction condensation using 2, 6-dimethyl-1, 4-benzoquinone and alkoxydiphenylphosphines.
Bulletin of the Chemical Society of Japan, 76(8), 1645-1667 (2003)
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