277371
1-(Trimethylsilyl)pyrrolidine
97%
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About This Item
Empirical Formula (Hill Notation):
C7H17NSi
CAS Number:
Molecular Weight:
143.30
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
239-149-3
Beilstein/REAXYS Number:
1304636
MDL number:
Assay:
97%
Form:
liquid
InChI key
NQLVIKZJXFGUET-UHFFFAOYSA-N
InChI
1S/C7H17NSi/c1-9(2,3)8-6-4-5-7-8/h4-7H2,1-3H3
SMILES string
C[Si](C)(C)N1CCCC1
assay
97%
form
liquid
refractive index
n20/D 1.433 (lit.)
bp
139-140 °C (lit.)
density
0.821 g/mL at 25 °C (lit.)
Application
1-(Trimethylsilyl)pyrrolidine (N-trimethylsilyl pyrrolidine) has been used in:
- ring opening reaction of L-serine β-lactone to yield corresponding 5-amino-L-alanine derivatives
- the preparation of iminium triflate salts
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
39.2 °F - closed cup
flash_point_c
4 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Regulatory Information
危险化学品
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Reaction of trimethylsilylamines with N-Cbz-l-serine-?-lactone: A convenient route to optically pure ?-amino-l-alanine derivatives.
Ratemi ES and Vederas JC.
Tetrahedron Letters, 35(41), 7605-7608 (1994)
Exocyclic iminium salts as catalysts for alkene epoxidation by Oxone?.
Armstrong A, et al.
Tetrahedron, 55(8), 2341-2352 (1999)
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