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Merck
CN

262587

Chloroplatinic acid solution

8 wt. % in H2O, liquid

Synonym(s):

Hexachloroplatinic acid solution, Hydrogen hexachloroplatinate(IV) solution, Platinic chloride solution, Platinum(IV) chloride solution

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About This Item

Linear Formula:
H2PtCl6
CAS Number:
16941-12-1
Molecular Weight:
409.81
UNSPSC Code:
12161600
PubChem Substance ID:
24855878
NACRES:
NA.22
MDL number:
MFCD00011330

Key Documents

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Product Name

Chloroplatinic acid solution, 8 wt. % in H2O

SMILES string

Cl.Cl.Cl[Pt](Cl)(Cl)Cl

InChI

1S/6ClH.Pt/h6*1H;/q;;;;;;+4/p-4

InChI key

GBFHNZZOZWQQPA-UHFFFAOYSA-J

form

liquid

reaction suitability

core: platinum
reagent type: catalyst

concentration

8 wt. % in H2O

density

1.05 g/mL at 25 °C

Quality Level

100

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Application

Chloroplatinic acid solution used as:
  • Platinum precursor in the synthesis of platinum nanoparticles using hydrazine as a reducing agent.
  • An electrolyte in the preparation of various carbon-supported platinum nanomaterials with H2SO4 by electrodeposition method in the presence or absence of organic additives.
  • An anionic precursor in the preparation of Pt/SBA_BEA catalyst for the hydro isomerization of n-hexadecane.
  • A Pt precursor in the preparation of PVP-protected Pt-nanoparticles by seed-mediated growth method.

General description

Chloroplatinicacid (H2PtCl6) is a hygroscopic inorganic compound that is widely used as a catalyst for hydrosilylation, hydrogenation, carbonylation, oxidation and coupling reactions.

Chloroplatinic acid solution catalyses the hydrosilylation reaction of 1-Hexyne to form l,6-Bis(trichlorosilyl)hexane.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Met. Corr. 1 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 2

target_organs

Kidney

Storage Class

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
MKCZ1847
MKCX8672
MKCX5029
MKCX0893
MKCV9415

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Preparation of size-tunable, highly monodisperse PVP-protected Pt-nanoparticles by seed-mediated growth
Koebel MM, et al.
Journal of Nanoparticle Research, 10(6), 1063-1069 (2008)
Precursor Design for High Density Single Pt Atom Sites on MoS2: Enhanced Stability at Elevated Temperatures and Reduced 3D Clustering
Xiang Li, et al.
Chemistry of Materials, 32(6) , 2541?2551-2541?2551 (2020)
The formation of 1, 6-bis (trichlorosilyl) hexane by the chloroplatinic acid catalyzed hydrosilylation of 1-hexyne
Benkeser RA, et al.
The Journal of Organic Chemistry, 32, 2634-2636 (1967)
Composite of Pt/AlSBA-15+ zeolite catalyst for the hydroisomerization of n-hexadecane: The effect of platinum precursor
Fedyna M, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 305, 110366-110366 (2020)
Investigation of the Effect of Different Organic Additives on Morphology and Electrocatalytic Activity of Platinum Nanomaterials Towards Oxygen Reduction Reactions
Belenov SV, et al.
Advanced Materials, 21-32 (2020)
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