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252913

Sigma-Aldrich

5,10,15,20-Tetrakis(pentafluorophenyl)-21H,23H-porphyrin iron(III) chloride

≥95% (HPLC)

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About This Item

Empirical Formula (Hill Notation):
C44H8ClF20FeN4
CAS Number:
Molecular Weight:
1063.83
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

≥95% (HPLC)

form

powder

reaction suitability

reagent type: catalyst
core: iron

λmax

415 nm
498 nm (2nd)

SMILES string

Fc1c(F)c(F)c(c(F)c1F)-c2c3ccc(n3)c(-c4c(F)c(F)c(F)c(F)c4F)c5ccc6c(-c7c(F)c(F)c(F)c(F)c7F)c8ccc(n8)c(-c9c(F)c(F)c(F)c(F)c9F)c%10ccc2n%10[Fe](Cl)n56

InChI

1S/C44H8F20N4.ClH.Fe/c45-25-21(26(46)34(54)41(61)33(25)53)17-9-1-2-10(65-9)18(22-27(47)35(55)42(62)36(56)28(22)48)12-5-6-14(67-12)20(24-31(51)39(59)44(64)40(60)32(24)52)16-8-7-15(68-16)19(13-4-3-11(17)66-13)23-29(49)37(57)43(63)38(58)30(23)50;;/h1-8H;1H;/q-2;;+3/p-1/b17-9+,17-11+,18-10+,18-12+,19-13+,19-15+,20-14+,20-16+;;

InChI key

RVNJZXLLVARDGN-VTVSBRCESA-M

Application

Catalyst for epoxidations with peroxides, oxidative decarbonylations, and aliphatic hydroxylations.

Features and Benefits

Catalyst for epoxidations with peroxides, oxidative decarbonylations, and aliphatic hydroxylations.
Preferred catalyst in catalytic oxygenation reactions.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Tetrahedron Letters, 33, 4949-4949 (1992)
Journal of the American Chemical Society, 115, 2775-2775 (1993)
Journal of the American Chemical Society, 114, 1308-1308 (1992)

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