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About This Item
Linear Formula:
C10H6(CH2Br)2
CAS Number:
Molecular Weight:
314.02
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
Assay
98%
form
crystals
mp
131-133 °C (lit.)
SMILES string
BrCc1cccc2cccc(CBr)c12
InChI
1S/C12H10Br2/c13-7-10-5-1-3-9-4-2-6-11(8-14)12(9)10/h1-6H,7-8H2
InChI key
GCZOMCDXYFMAGP-UHFFFAOYSA-N
General description
Two-photon chemistry of 1,8-bis(bromomethyl)naphthalene has been studied by time-delayed, two-color photolysis and argon ion laser-jet photolysis techniques.
Application
1,8-Bis(bromomethyl)naphthalene has been used in the synthesis of indan-based unusual α-amino acid derivatives under solid-liquid phase-transfer catalysis conditions.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Certificates of Analysis (COA)
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Two-Photon Laser-Induced Reaction of 1, 8-Bis (halomethyl) naphthalenes from Different Excited States and Transient Targeting of Its Intermediate by Time-Delayed, Two-Color Photolysis and Argon Ion Laser-Jet Photolysis Techniques
Ouchi A, et al.
Journal of the American Chemical Society, 119(3), 592-599 (1997)
S Kotha et al.
The Journal of organic chemistry, 65(5), 1359-1365 (2000-05-18)
Conformationally constrained cyclic alpha-amino acid derivatives were synthesized under solid-liquid phase-transfer catalysis conditions. This methodology involves the bis-alkylation of ethyl isocyanoacetate with various alpha,alpha'-dibromo-o-xylene derivatives [alpha,alpha'-dibromo-o-xylene 5, 2,3-bis(bromomethyl)-1, 4-dimethoxybenzene 6, 1,2-bis(bromomethyl)-4,5-dibromobenzene 7, 2, 3-bis(bromomethyl)naphthalene 8, 1,8-bis(bromomethyl)-naphthalene 9, 6,7-bis(bromomethyl)-2,2-dimethyl-1H-phenalene-1,3(2H)-dione 10, 2
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