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751618

Sigma-Aldrich

MorDalphos

97%

别名:

二(1-金刚烷基)-2-吗啉代苯基膦

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About This Item

经验公式（希尔记法）:
C30H42NOP
CAS号:
1237588-12-3
分子量:
463.63
MDL编号:
MFCD17018759
UNSPSC代码:
12352005
PubChem化学物质编号:
329766227
NACRES:
NA.22

质量水平

100

方案

97%

表单

solid

反应适用性

reagent type: ligand
reaction type: Arylations
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction

mp

219-224 °C

官能团

phosphine

储存温度

2-8°C

SMILES字符串

C1CN(CCO1)c2ccccc2P([C@@]34C[C@@H]5C[C@@H](C[C@@H](C5)C3)C4)[C@@]67C[C@@H]8C[C@@H](C[C@@H](C8)C6)C7

InChI

1S/C30H42NOP/c1-2-4-28(27(3-1)31-5-7-32-8-6-31)33(29-15-21-9-22(16-29)11-23(10-21)17-29)30-18-24-12-25(19-30)14-26(13-24)20-30/h1-4,21-26H,5-20H2/t21-,22+,23-,24-,25+,26-,29-,30-

InChI key

CCBRRSUORFMQCZ-BVIFAWIJSA-N

相关类别

应用

MorDalphos是由Stradiotto集团所开发的一种富电子、受空间阻碍的P,N-基辅助配体，可用于Buchwald-Hartwig胺化反应、炔烃加氢胺化以及氨，肼和丙酮等化合物的单芳基化。

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产品编号
说明
价格

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SHBQ2119
SHBL0922
SHBJ6164
SHBH8248
SHBH2274V

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Rational and Predictable Chemoselective Synthesis of Oligoamines via Buchwald?Hartwig Amination of (Hetero) Aryl Chlorides Employing Mor-DalPhos.
Tardiff B, et al.
The Journal of Organic Chemistry, 77(2), 1056-1071 (2011)
Palladium-catalyzed mono-?-arylation of acetone with aryl halides and tosylates.
Hesp K D, et al.
Journal of the American Chemical Society, 133(14), 5194-5197 (2011)
Stereo-and regioselective gold-catalyzed hydroamination of internal alkynes with dialkylamines.
Hesp K D, et al.
Journal of the American Chemical Society, 132(51), 18026-18029 (2010)
AP, N?Ligand for Palladium?Catalyzed Ammonia Arylation: Coupling of Deactivated Aryl Chlorides, Chemoselective Arylations, and Room Temperature Reactions
Lundgren R J, et al.
Angewandte Chemie (International Edition in English), 122(24), 4165-4168 (2010)

商品

DalPhos Ligands

DalPhos ligands enable Pd-catalyzed C-N and C-C bond formation with good functional group tolerance.

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Stradiotto group focuses on electronically rich ligands for late metal catalysis, including Pd and Au chemistry applications.

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