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Merck
CN

723010

Sigma-Aldrich

2-(十二烷基三硫代碳酸酯基)-2-甲基丙酸

98% (HPLC)

别名:

2-(十二烷基三硫代碳酸酯基)-2-异丁酸, 十二烷基- '-(α,α'-二甲基α''乙酸)三硫代碳酸酯, DDMAT

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About This Item

经验公式(希尔记法):
C17H32O2S3
分子量:
364.63
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.23

方案

98% (HPLC)

表单

powder

mp

57-63 °C

储存温度

2-8°C

SMILES字符串

CCCCCCCCCCCCSC(=S)SC(C)(C)C(O)=O

InChI

1S/C17H32O2S3/c1-4-5-6-7-8-9-10-11-12-13-14-21-16(20)22-17(2,3)15(18)19/h4-14H2,1-3H3,(H,18,19)

InChI key

DZFGVGDQHQHOKZ-UHFFFAOYSA-N

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一般描述

想要选择最佳的 RAFT 试剂?请查询单体相容性表,以便进行正确的 选择。

应用

RAFT可控自由基聚合助剂,特别适用于苯乙烯、丙烯酸酯、丙烯酰胺单体的聚合。 链转移剂(CTA)

象形图

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警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

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Haichao Duan et al.
Nanoscale, 10(26), 12487-12496 (2018-06-22)
Well-dispersed ultrafine palladium nanoparticles supported by reduced graphene oxide functionalized with catechol-terminated thermo-responsive block copolymer (PdNPs@BPrGO) were successfully constructed for highly efficient heterogeneous catalytic reduction. We first synthesized a novel temperature-responsive episulfide-containing double-hydrophilic diblock copolymer, poly(poly(ethylene glycol) methyl ether methacrylate-co-2,3-epithiopropyl
Chloé Grazon et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 18(5), 1156-1165 (2019-02-26)
A new ratiometric fluorescent pH nanosensor is presented. It is based on ultrabright nanoparticles containing two spatially separated fluorophores: BODIPY covalently linked to the polystyrene core and fluorescein grafted to the nanoparticle shell. The nanoparticles comprise a large number (≥2500)
Wenyan Wang et al.
Carbohydrate polymers, 207, 239-245 (2019-01-03)
This study reports on eco-friendly graft polymerization approach for the modification of a cellulosic material via combination between enzymatic catalysis and reversible addition-fragmentation chain transfer polymerization (RAFT). Polyacrylamide (PAM) was polymerized on a cellulosic filter paper via horseradish peroxidase (HRP)-initiated
Po-Chih Yang et al.
Polymers, 11(12) (2019-12-11)
This paper gathered studies on multistimulus-responsive sensing and self-assembly behavior of a novel amphiphilic diblock copolymer through a two-step reverse addition-fragmentation transfer (RAFT) polymerization technique. N-Isopropylacrylamide (NIPAM) macromolecular chain transfer agent and diblock copolymer (poly(NIPAM-b-Azo)) were discovered to have moderate
Despoina Giaouzi et al.
Polymers, 12(6) (2020-06-25)
In this work, the synthesis, selective chemical modifications, and self-assembly behavior in aqueous media of a novel poly(2-(dimethylamino)ethyl acrylate)20-b-poly(N-isopropylacrylamide)11-b-poly(oligo ethylene glycol methyl ether acrylate)18 (PDMAEA20-b-PNIPAM11-b-POEGA18) dual-responsive (pH and temperature) and triply hydrophilic amino-based triblock terpolymer are reported. The amine functional

商品

RAFT polymerization uses commercial agents to control polymer properties without cytotoxic heavy metals like ATRP.

RAFT(可逆加成断裂链转移)聚合是一种可逆的去活化自由基聚合(RDRP),是给自由基聚合赋予活性的通用方法之一。

RAFT polymerization offers living characteristics to radical polymerization, contributing versatility to reversible deactivation radical polymerization methods.

Over the past two decades, the rapid advance of controlled living polymerization (CLP) techniques.

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实验方案

RAFT(可逆加成-断裂链转移)是一种活性自由基聚合反应,在有适合的连转移(RAFT)试剂存在下发生的非传统的取代单体自由基聚合反应。

RAFT polymerization offers precise control, enabling tailored synthesis of complex polymer structures.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

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