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Merck
CN

723002

Sigma-Aldrich

氰甲基甲基(苯基)氨基二硫代甲酸酯

98% (HPLC)

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别名:
N-甲基-N-苯基二硫代氨基甲酸氰甲基酯
经验公式(希尔记法):
C10H10N2S2
CAS号:
分子量:
222.33
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.23

质量水平

检测方案

98% (HPLC)

形式

powder

分子量

average Mn 8,000

mp

88-92 °C

储存温度

2-8°C

SMILES字符串

CN(C(=S)SCC#N)c1ccccc1

InChI

1S/C10H10N2S2/c1-12(10(13)14-8-7-11)9-5-3-2-4-6-9/h2-6H,8H2,1H3

InChI key

FYACMHCOSCVNHO-UHFFFAOYSA-N

一般描述

需要获取帮助以选择合适的 RAFT 试剂吗?请查阅 RAFT 试剂与单体相容性表格

应用

用于受控自由基聚合的RAFT试剂,特别适用于乙烯基酯和乙烯基酰胺单体的聚合。 链转移剂(CTA)

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Skin Sens. 1

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

商品

Low-cost, high-purity RAFT Agents are vital for industrial RAFT polymerization. We supply effective agents for this technology.

RAFT polymerization uses commercial agents to control polymer properties without cytotoxic heavy metals like ATRP.

RAFT(可逆加成断裂链转移)聚合是一种可逆的去活化自由基聚合(RDRP),是给自由基聚合赋予活性的通用方法之一。

RAFT polymerization offers living characteristics to radical polymerization, contributing versatility to reversible deactivation radical polymerization methods.

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实验方案

RAFT(可逆加成-断裂链转移)是一种活性自由基聚合反应,在有适合的连转移(RAFT)试剂存在下发生的非传统的取代单体自由基聚合反应。

RAFT polymerization offers precise control, enabling tailored synthesis of complex polymer structures.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

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