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Merck
CN
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文件

722995

Sigma-Aldrich

4-氰基-4-（苯基羰基硫）戊酸

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别名:
4-氰基-4-(硫代苯甲酰)戊酸
经验公式（希尔记法）:
C13H13NO2S2
CAS号:
201611-92-9
分子量:
279.38
MDL编号:
MFCD10698690
UNSPSC代码:
12352100
PubChem化学物质编号:
329763966
NACRES:
NA.23

形式

powder

质量水平

100

mp

94-98 °C

储存温度

2-8°C

SMILES字符串

CC(CCC(O)=O)(SC(=S)c1ccccc1)C#N

InChI

1S/C13H13NO2S2/c1-13(9-14,8-7-11(15)16)18-12(17)10-5-3-2-4-6-10/h2-6H,7-8H2,1H3,(H,15,16)

InChI key

YNKQCPNHMVAWHN-UHFFFAOYSA-N

相关类别

一般描述

4-氰基-4-（苯基硫代甲酰硫基）戊酸是一种硫基链转移剂，为活性自由基聚合提供了高度控制。

应用

可逆加成断裂链转移 (RAFT)聚合
可控自由基聚合的RAFT剂；特别适用于甲基丙烯酸酯和甲基丙烯酰胺单体的聚合。

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H317

预防措施声明

P280

危险分类

Skin Sens. 1

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable

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Chunyun Wang et al.
Drug delivery, 27(1), 344-357 (2020-02-25)
Stimuli-responsive drug delivery systems (DDSs) are expected to realize site-specific drug release and kill cancer cells selectively. In this study, a pH-responsive micelle was designed utilizing the pH-sensitivity of borate bonds formed between dopamine and boronic acid. First, methyl (polyethylene
Sieun Kim et al.
Biomacromolecules, 21(8), 3026-3037 (2020-07-17)
Charge anisotropy or the presence of charge patches at protein surfaces has long been thought to shift the coacervation curves of proteins and has been used to explain the ability of some proteins to coacervate on the "wrong side" of
Bartlomiej Kalaska et al.
Translational research : the journal of laboratory and clinical medicine, 177, 98-112 (2016-07-28)
The parenteral anticoagulants may cause uncontrolled and life-threatening bleeding. Protamine, the only registered heparin antidote, is partially effective against low-molecular weight heparins, completely ineffective against fondaparinux and may cause unacceptable toxicity. Therefore, we aimed to develop a synthetic compound for
Hui-Yu Liu et al.
Molecules (Basel, Switzerland), 25(12) (2020-06-19)
Biomimetic lipid membranes on solid supports have been used in a plethora of applications, including as biosensors, in research on membrane proteins or as interfaces in cell experiments. For many of these applications, structured lipid membranes, e.g., in the form
Xinnan Cui et al.
Colloids and surfaces. B, Biointerfaces, 160, 289-296 (2017-09-26)
Four types of phosphorylated 2-hydroxyethyl methacrylate and poly(ethylene glycol) methyl ether methacrylate (PEGMA) block copolymers were synthesized by reversible addition fragmentation chain transfer (RAFT) polymerization and post-phosphorylation. These polymers were composed of different phosphate segments and similar PEG brushes. Polymers
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商品

Convert to mPAGE™ Gels for Improved Results

RAFT polymerization uses commercial agents to control polymer properties without cytotoxic heavy metals like ATRP.

逆加成-断裂链转移 (RAFT)聚合

RAFT（可逆加成断裂链转移）聚合是一种可逆的去活化自由基聚合（RDRP），是给自由基聚合赋予活性的通用方法之一。

RAFT Polymerization

RAFT polymerization offers living characteristics to radical polymerization, contributing versatility to reversible deactivation radical polymerization methods.

Functional Biomaterials Synthesized by Double-Head Polymerization Agents

Over the past two decades, the rapid advance of controlled living polymerization (CLP) techniques.

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实验方案

RAFT聚合反应操作步骤

RAFT（可逆加成-断裂链转移）是一种活性自由基聚合反应，在有适合的连转移（RAFT）试剂存在下发生的非传统的取代单体自由基聚合反应。

RAFT Polymerization Procedures

RAFT polymerization offers precise control, enabling tailored synthesis of complex polymer structures.

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Concepts and Tools for RAFT Polymerization

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

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