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经验公式(希尔记法):
C9H18Cl2LiMgN
化学文摘社编号:
分子量:
242.40
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI
1S/C9H18N.2ClH.Li.Mg/c1-8(2)6-5-7-9(3,4)10-8;;;;/h5-7H2,1-4H3;2*1H;;/q-1;;;+1;+2/p-2
SMILES string
[Li+].[Cl-].CC1(C)CCCC(C)(C)N1[Mg]Cl
InChI key
JHBZAAACZVPPRQ-UHFFFAOYSA-L
form
liquid
reaction suitability
reaction type: Grignard Reaction
concentration
1.0 M in THF, 20 % (w/w)
density
0.96 g/mL at 25 °C
storage temp.
2-8°C
Quality Level
Application
2,2,6,6-四甲基哌啶基氯化镁氯化锂复合物是非亲核性Knochel-Hauser碱, 主要用于官能化芳烃和杂芳烃的氧化,以制备相应的格氏试剂。它还可以用作通过催化剂转移缩聚合成Π-共轭聚合物过程的碱。
Packaging
建议将25 mL Sure/Seal™ 瓶作为一次性包装瓶使用。 反复穿刺可能导致产品性能下降。
Legal Information
Albemarle US Inc.产品
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
flash_point_f
5.0 °F
flash_point_c
-15 °C
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Central nervous system, Respiratory system
法规信息
危险化学品
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商品
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