形式
liquid
质量水平
反应适用性
reaction type: Grignard Reaction
浓度
1.0 M in THF/toluene
20 % (w/w)
密度
0.96 g/mL at 25 °C
储存温度
2-8°C
SMILES字符串
[Li+].[Cl-].CC1(C)CCCC(C)(C)N1[Mg]Cl
InChI
1S/C9H18N.2ClH.Li.Mg/c1-8(2)6-5-7-9(3,4)10-8;;;;/h5-7H2,1-4H3;2*1H;;/q-1;;;+1;+2/p-2
InChI key
JHBZAAACZVPPRQ-UHFFFAOYSA-L
应用
2,2,6,6-四甲基哌啶基氯化镁氯化锂复合物是非亲核性Knochel-Hauser碱, 主要用于官能化芳烃和杂芳烃的氧化,以制备相应的格氏试剂。它还可以用作通过催化剂转移缩聚合成Π-共轭聚合物过程的碱。
包装
建议将25 mL Sure/Seal™ 瓶作为一次性包装瓶使用。 反复穿刺可能导致产品性能下降。
法律信息
Albemarle US Inc.产品
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
警示用语:
Danger
危险分类
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT SE 3
靶器官
Respiratory system
补充剂危害
储存分类代码
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 3
闪点(°F)
5.0 °F
闪点(°C)
-15 °C
法规信息
危险化学品
Highly Functionalized Benzene Syntheses by Directed Mono or Multiple Magnesiations with TMPMgCl.LiCl.
Organic Letters, 8(24), 5673-5676 (2006)
Direct, regioselective N-alkylation of 1, 3-azoles.
Organic Letters, 18(1), 16-19 (2015)
Scientific reports, 7, 39937-39937 (2017-01-07)
Processing and manipulation of highly conductive pristine graphene in large quantities are still major challenges in the practical application of graphene for electric device. In the present study, we report the liquid-phase exfoliation of graphite in toluene using well-defined poly(3-hexylthiophene)
Conjugated Polymers with Repeated Sequences of Group 16 Heterocycles Synthesized through Catalyst-Transfer Polycondensation.
Journal of the American Chemical Society, 138(21), 6798-6804 (2016)
Scaleable preparation of functionalized organometallics via directed ortho metalation using Mg-and Zn-amide bases.
Organic Process Research & Development, 14(2), 339-345 (2010)
商品
Transformative reagents enable selective conversions within molecules containing sensitive functionalities under mild reactions.
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