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Merck
CN

406023

Sigma-Aldrich

二乙基锌 溶液

1.0 M in heptane

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别名:
Zincdiethyl
线性分子式:
(C2H5)2Zn
CAS号:
分子量:
123.51
Beilstein:
3587207
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22

形式

liquid

质量水平

浓度

1.0 M in heptane

bp

98 °C

密度

0.74 g/mL at 25 °C

SMILES字符串

CC[Zn]CC

InChI

1S/2C2H5.Zn/c2*1-2;/h2*1H2,2H3;

InChI key

HQWPLXHWEZZGKY-UHFFFAOYSA-N

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应用

二乙基锌溶液可用于合成:
  • 双(吡啶基吡咯基)锌发光配合物。
  • 通用构件块,5-(酮芳基)噻唑。
  • 具有高发光性能的 ZnxCd1-xSe 纳米晶体。

警示用语:

Danger

危险分类

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1

靶器官

Central nervous system

补充剂危害

WGK

WGK 3

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

分析证书(COA)

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Pyridylpyrrolides as alternatives to cyclometalated phenylpyridine ligands: synthesis and characterization of luminescent zinc and boron pyridylpyrrolide complexes.
Klappa JJ, et al.
Dalton Transactions, 883-891 (2004)
Composition-Tunable ZnxCd1-xSe nanocrystals with high luminescence and stability.
Xinhua Z, et al.
Journal of the American Chemical Society, 125(28), 8589-8594 (2003)
Practical synthesis of a highly functionalized thiazole ketone.
Frey LF, et al.
Tetrahedron, 59(33), 6363-6373 (2003)
Weimin Lin et al.
The Journal of organic chemistry, 74(2), 645-651 (2008-12-06)
The application of a zinc carbenoid-mediated chain-extension reaction to a functionalized peptide isostere is reported. The cleavage site of human CVM protease was utilized as a target for testing the synthetic methodology. The utility of this chain-extension reaction is demonstrated
Tummanapalli Satyanarayana et al.
Organic letters, 9(2), 251-253 (2007-01-16)
A strong asymmetric amplification is observed in the addition of diethylzinc on aromatic aldehydes in the presence of the bistriflamide of trans-1,2-diaminocyclohexane 3a. The asymmetric amplification originates from the insolubility of the catalyst precursor 3a of low enantiomeric excess (ee)

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