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Merck
CN

364673

乙基溴化镁 溶液

1.0 M in THF

别名:

EtMgBr溶液

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关于此项目

线性分子式:
CH3CH2MgBr
化学文摘社编号:
分子量:
133.27
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3587203
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产品名称

乙基溴化镁 溶液, 1.0 M in THF

InChI

1S/C2H5.BrH.Mg/c1-2;;/h1H2,2H3;1H;/q;;+1/p-1

SMILES string

CC[Mg]Br

InChI key

TWTWFMUQSOFTRN-UHFFFAOYSA-M

form

liquid

reaction suitability

reaction type: Grignard Reaction

concentration

1.0 M in THF

density

1.010 g/mL at 25 °C

Quality Level

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Application

乙基溴化镁溶液可用于格氏反应以及其他格氏试剂的合成。

Other Notes

25℃以下储存可能会形成镁盐结晶。将容器移到温暖的位置,偶尔轻轻旋转,应该能使固体重新溶解。

Packaging

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1

target_organs

Respiratory system

supp_hazards

存储类别

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 1

flash_point_f

23.0 °F - closed cup

flash_point_c

-5 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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An improved synthesis of (+)-3, 4-O-isopropylidene butyne.
Jiang B
Synthetic Communications, 25(22), 3641-3645 (1995)
Replacement of the lactone moiety on podophyllotoxin and steganacin analogues with a 1, 5-disubstituted 1, 2, 3-triazole via ruthenium-catalyzed click chemistry.
Imperio D
Bioorganic & Medicinal Chemistry, 15(21), 6748-6757 (2007)
D R Hwang et al.
Nuclear medicine and biology, 27(6), 533-539 (2000-11-01)
Imaging neuroreceptors with radiolabeled agonists might provide valuable information on the in vivo agonist affinity states of receptors of interest. We report here the radiosynthesis, biodistribution in rodents, and imaging studies in baboons of [(11)C]-labeled (-)-N-propyl-norapomorphine [(-)-NPA]. (-)-[(11)C]NPA was prepared
Janne E Tønder et al.
Organic & biomolecular chemistry, 2(10), 1447-1455 (2004-05-12)
Copper mediated allylic substitutions and conjugate additions to geranyl, cinnamyl and allylic indole compounds have been investigated with the aim of finding a method for the creation of the all-carbon quaternary centre present in the natural product lyngbyatoxin A. Reaction
M Wältermann et al.
Microbiology (Reading, England), 146 ( Pt 5), 1143-1149 (2000-06-01)
The triacylglycerol (TAG)-accumulating, hydrocarbon-degrading bacterium Rhodococcus opacus strain PD630 and chemically induced storage-deficient mutants derived from this strain were investigated for their capability to accumulate storage lipids in the cytoplasm during cultivation under nitrogen-limiting conditions. Acylglycerols were analysed by matrix-associated

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