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254185

Sigma-Aldrich

溴化铜

99.999% trace metals basis

别名:

一溴化铜

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About This Item

线性分子式:
CuBr
CAS号:
7787-70-4
分子量:
143.45
EC 号:
232-131-6
MDL编号:
MFCD00010969
UNSPSC代码:
12352302
PubChem化学物质编号:
24855364
NACRES:
NA.23
方案:
99.999% trace metals basis
表单:
powder

质量水平

200

方案

99.999% trace metals basis

表单

powder

反应适用性

reagent type: catalyst
core: copper

杂质

≤15.0 ppm Trace Metal Analysis

mp

504 °C (lit.)

密度

4.71 g/mL at 25 °C (lit.)

应用

battery manufacturing

SMILES字符串

[Cu]Br

InChI

1S/BrH.Cu/h1H;/q;+1/p-1

InChI key

NKNDPYCGAZPOFS-UHFFFAOYSA-M

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相关类别

一般描述

溴化亚铜(I)是一种淡绿色的无机抗磁性固体，具有像硫化锌一样的聚合结构。不溶于水，广泛应用于催化、纳米材料合成和太阳能电池等领域。

应用

溴化亚铜(I)可用于：
  • 作为有机太阳能电池（OSC）的溶液可加工空穴传输层（HTL）。CuBr可提高太阳能电池的能量转换效率。
  • 作为合成光致发光金属有机框架（MOF）的前体。
  • 合成高发光性三配位铜(I)配合物作为OLED的掺杂剂，其最大外部量子效率为21.3%。
  • 与配体作为催化剂在14种不同溶剂中进行叔烷基卤化物的原子转移自由基聚合（ATRP）反应，测定速率常数。
  • 分子内自由基陷阱辅助原子转移自由基偶联法合成大环聚合物。

警示用语：

Danger

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
0000391142
0000325847
0000391142
0000325847
0000244838

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An acs-Type Metal--Organic Framework with an Unprecedented Undecanuclear Copper Cluster as Secondary Building Unit
Sheng Hu, et al.
European Journal of Inorganic Chemistry, 2012, 3669-3673 (2012)
Highly Efficient Green Organic Light-Emitting Diodes Containing Luminescent Three-Coordinate Copper(I) Complexes
Masashi Hashimoto, et al.
Journal of the American Chemical Society, 133, 10348-10351 (2011)
Copper Bromide as an Efficient Solution-Processable Hole Transport Layer for Organic Solar Cells: Effect of Solvents
Ranoo Bhargav, et al.
ACS Omega, 4, 6028-6034 (2019)
Carla Sardo et al.
International journal of pharmaceutics, 563, 347-357 (2019-04-03)
Sustained pulmonary delivery of tobramycin from microparticles composed of drug/polymer nanocomplexes offers several advantages against traditional delivery methods. Namely, in patients with cystic fibrosis, microparticle delivery can protect the tobramycin being delivered from strong mucoadhesive interactions, thus avoiding effects on
Denissova I and Barriault L et al.
Handbook of Reagents for Organic Synthesis null
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