- Versatile synthesis of end-reactive polyrotaxanes applicable to fabrication of supramolecular biomaterials.
Versatile synthesis of end-reactive polyrotaxanes applicable to fabrication of supramolecular biomaterials.
Beilstein journal of organic chemistry (2017-02-02)
Atsushi Tamura, Asato Tonegawa, Yoshinori Arisaka, Nobuhiko Yui
PMID28144361
ABSTRACT
Cyclodextrin (CD)-threaded polyrotaxanes (PRXs) with reactive functional groups at the terminals of the axle polymers are attractive candidates for the design of supramolecular materials. Herein, we describe a novel and simple synthetic method for end-reactive PRXs using bis(2-amino-3-phenylpropyl) poly(ethylene glycol) (PEG-Ph-NH