V900131
CDI
Vetec™, reagent grade, 97%
Synonym(s):
1,1′-Carbonyldiimidazole
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About This Item
Empirical Formula (Hill Notation):
C7H6N4O
CAS Number:
Molecular Weight:
162.15
EC Number:
208-488-9
UNSPSC Code:
12352115
PubChem Substance ID:
Beilstein/REAXYS Number:
6826
MDL number:
InChI key
PFKFTWBEEFSNDU-UHFFFAOYSA-N
InChI
1S/C7H6N4O/c12-7(10-3-1-8-5-10)11-4-2-9-6-11/h1-6H
SMILES string
O=C(n1ccnc1)n2ccnc2
grade
reagent grade
product line
Vetec™
assay
97%
mp
117-122 °C (lit.)
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Application
CDI can be used:
- To decarboxylate malonic acid derivatives to yield carbonyl imidazole moiety, which can further be reacted with different nucleophiles.
- To activate cellulose membranes, which are used in immunosensor applications.
- To functionalize Fe3O4-SiO2 core-shell nanoparticles for bio-applications.
- To prepare syn- and anti-1,2-imidazolylpropylamines by reacting with syn- and anti-1,2-amino alcohols.
- In the preparation of N-substituted imidazole derivatives, which are further used to prepare new ionic liquids.
Legal Information
Vetec is a trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
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Synthesis and surface functionalization of Fe3O4-SiO2 core-shell nanoparticles with 3-glycidoxypropyltrimethoxysilane and 1, 1′-carbonyldiimidazole for bio-applications
Ta TKH, et al.
Colloids and Surfaces. A, Physicochemical and Engineering Aspects, 504(2), 376-383 (2016)
1, 1′-Carbonyldiimidazole mediates the synthesis of N-substituted imidazole derivatives from Morita--Baylis--Hillman adducts
Rodrigues Jr MT, et al.
Tetrahedron Letters, 55(1), 180-183 (2014)
Regio-and Stereospecific Syntheses of syn-and anti-1, 2-Imidazolylpropylamines from the Reaction of 1, 1′-Carbonyldiimidazole with syn-and anti-1, 2-Amino Alcohols
Mulvihill MJ, et al.
The Journal of Organic Chemistry, 69(15), 5124-5127 (2004)
Daniela Stöllner et al.
Analytical biochemistry, 304(2), 157-165 (2002-05-16)
Methods for the activation of a cellulose dialysis membrane for immunosensor applications have been developed. For activation two reagents, 1,1'-carbonyldiimidazole (CDI) and 1-cyano-4-dimethylaminopyridinium tetrafluoroborate (CDAP), were compared with respect to the coupling efficiency for glucose oxidase (GOx) and 1,8-diamino-2,6-dioxaoctane. The
Thomas-Xavier Métro et al.
Chemical communications (Cambridge, England), 48(96), 11781-11783 (2012-10-31)
The synthesis of various amides has been realised avoiding the use of any organic solvent from activation of carboxylic acids with CDI to isolation of the amides. Mechanochemistry was the key point of the process allowing rapid formation of the
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