CRM44794
Phosphamidon
certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
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Synonym(s):
2-Chloro-N,N-diethyl-3-(dimethylphosphono)crotonic amide
Empirical Formula (Hill Notation):
C10H19ClNO5P
CAS Number:
Molecular Weight:
299.69
Beilstein:
8323501
MDL number:
UNSPSC Code:
41116107
NACRES:
NA.24
Recommended Products
grade
certified reference material
TraceCERT®
Quality Level
product line
TraceCERT®
shelf life
limited shelf life, expiry date on the label
manufacturer/tradename
Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
format
neat
storage temp.
−20°C
SMILES string
CCN(CC)C(=O)\C(Cl)=C(\C)OP(=O)(OC)OC
InChI
1S/C10H19ClNO5P/c1-6-12(7-2)10(13)9(11)8(3)17-18(14,15-4)16-5/h6-7H2,1-5H3/b9-8+
InChI key
RGCLLPNLLBQHPF-CMDGGOBGSA-N
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General description
This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Phosphamidon is a broad-spectrum systemic organophosphorus pesticide. It is used as an insecticide against sap-feeding insects, rice-stem borers, and rice leaf beetles in crops of sugarcane, citrus fruits, commercial cotton, and nuts.
As per Regulation (EC) No. 1107/2009, repealing directive 91/414/EEC, phosphamidon is not approved for use in the European Union. But a default maximum residue limit (MRL) of 0.01 mg/kg is applicable for the presence of phosphamidon in products of plant origin, in accordance with Regulation (EC) No. 149/2008.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Phosphamidon is a broad-spectrum systemic organophosphorus pesticide. It is used as an insecticide against sap-feeding insects, rice-stem borers, and rice leaf beetles in crops of sugarcane, citrus fruits, commercial cotton, and nuts.
As per Regulation (EC) No. 1107/2009, repealing directive 91/414/EEC, phosphamidon is not approved for use in the European Union. But a default maximum residue limit (MRL) of 0.01 mg/kg is applicable for the presence of phosphamidon in products of plant origin, in accordance with Regulation (EC) No. 149/2008.
Application
The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The phosphamidon CRM may also find following uses:
The phosphamidon CRM may also find following uses:
- Determination of five organophosphorus pesticides in a medicinal herb sample using QuEChERS along with dispersive liquid-liquid microextraction (DLLME) and stacking followed by micellar electrokinetic chromatography (MEKC)
- Magnetic solid phase microextraction (MSPE) of five organophosphorus pesticides using graphene based cyanopropyltriethoxysilane as an adsorbent from cow′s milk samples and their subsequent determination by gas chromatography with micro-electron capture detector
- Investigation of residue levels of highly toxic pesticides in 6554 samples of fruits and vegetables by quadrupole time-of-flight LC/MS
- Analysis of 4 organophosphorus pesticides by gas chromatography with microelectron capture detector following their extraction using a newly synthesized magnetic hybrid material as a solid phase extraction adsorbent
- Multi-residue analysis of 44 organophosphorus pesticides by QuEChERS method combined with gas chromatography in Pogostemon cablin samples
- Detection of organophosphorus pesticides in Chinese cabbage sample by a newly designed positive photoionization-ion mobility spectrometry (PP-IMS) apparatus
Legal Information
TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Muta. 2
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Regulatory Information
监管及禁止进口产品
Certificates of Analysis (COA)
Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.
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Qinghua Zhou et al.
Talanta, 176, 247-252 (2017-09-18)
Ion mobility spectrometry (IMS) opened a potential avenue for the rapid detection of organophosphorus pesticides (OPPs), though an improved selectivity of stand-alone IMS was still in high demand. In this study, a stand-alone positive photoionization ion mobility spectrometry (PP-IMS) apparatus
Photocatalytic degradation of phosphamidon using Ag-doped ZnO nanorods
Korake PV, et al.
Toxicological & Environmental Chemistry, 94(6), 1075-1085 (2012)
Somayeh Koupaei Malek et al.
Journal of separation science (2018-06-08)
The precise control of pesticide residues in foodstuffs depends significantly on the clean extraction of analytes using specifically designed separation methods. In this study, a one-pot sol-gel process was used for the preparation of a magnetic hybrid silica gel tetraethylortho
Magnetic graphene-based cyanopropyltriethoxysilane as an adsorbent for simultaneous determination of polar and non-polar organophosphorus pesticides in cow?s milk
Nodeh H R, et al.
Royal Society of Chemistry Advances, 6(30), 24853-24864 (2016)
Trace determination of five organophosphorus pesticides by using QuEChERS coupled with dispersive liquid-liquid microextraction and stacking before micellar electrokinetic chromatography
Wei J, et al.
Analytical Methods : Advancing Methods and Applications, 7(14), 5801-5807 (2015)
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