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Safety Information

48029

Supelco

3,3′-Dichlorobenzidine solution

certified reference material, 2000 μg/mL in methanol

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About This Item

Empirical Formula (Hill Notation):
C12H10Cl2N2
CAS Number:
91-94-1
Molecular Weight:
253.13
UNSPSC Code:
12000000

grade

certified reference material
TraceCERT®

product line

TraceCERT®

CofA

current certificate can be downloaded

feature

standard type calibration

packaging

ampule of 1 mL

concentration

2000 μg/mL in methanol

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

cleaning products
cosmetics
environmental
food and beverages
personal care

format

single component solution

storage temp.

2-8°C

InChI

1S/C12H10Cl2N2/c13-9-5-7(1-3-11(9)15)8-2-4-12(16)10(14)6-8/h1-6H,15-16H2

InChI key

HUWXDEQWWKGHRV-UHFFFAOYSA-N

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General description

3,3′-Dichlorobenzidine is a persistent hydrophobic organic contaminant, found to be carcinogenic in nature and is released into the environment as an intermediate from dye manufacturing processes.

Application

3,3′-Dichlorobenzidine may be used as a certified reference standard for the quantification of the analyte and its congeners in environmental samples using high-performance liquid chromatography technique.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Other Notes

This Certified Reference Material (CRM) is produced and certified in accordance with ISO 17034 and ISO/IEC 17025. All information regarding the use of this CRM can be found on the certificate of analysis.

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 3 - Carc. 1B - Flam. Liq. 2 - STOT SE 1

Target Organs

Eyes

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Regulatory Information

危险化学品

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Certificates of Analysis (COA)

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3,3'-Dichlorobenzidine and its dihydrochloride.
Report on carcinogens : carcinogen profiles, 12, 141-143 (2011-08-19)
Lei Wang et al.
Toxicology, 207(3), 411-418 (2005-01-25)
DCB, 3,3'-dichlorobenzidine, is used primarily as an intermediate in the manufacture of diarylide yellow or azo red pigments for printing ink, textile, paint, and plastics. It is also used in tattoo inks. In this article, we investigate light-induced toxicity of
3,3'-Dichlorobenzidine and 3,3'-dichlorobenzidine dihydrochloride.
Report on carcinogens : carcinogen profiles, 11, III87-III89 (2004-01-01)
T Hofmann et al.
Archives of toxicology, 67(2), 141-144 (1993-01-01)
Rats were exposed by inhalation to the technically highest administrable concentration of 230 mg Pigment Yellow 17/m3 air for 4 h. Inhalability of the dust was guaranteed by a mass-median aerodynamic diameter of 1.0-1.1 microns. For 14 days after exposure
P Sagelsdorff et al.
Carcinogenesis, 17(3), 507-514 (1996-03-01)
The hypothetical release of 3,3'-dichlorobenzidine (DCB) from two insoluble azo pigments and from a soluble azo dye was investigated in female Wistar rats for a 4 week treatment with 0.2% (w/w) Colour Index Pigment 13 (PY13) or 0.2% (w/w) Colour
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