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Merck
CN

33355

Methanolic HCl

3 M HCl in methanol (3N), derivatization grade (GC derivatization), ampule of 20 × 1 mL

Synonym(s):

Hydrochloric acid solution

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About This Item

Empirical Formula (Hill Notation):
HCl
CAS Number:
7647-01-0
Molecular Weight:
36.46
UNSPSC Code:
41116105
PubChem Substance ID:
24860145

Key Documents

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Product Name

Methanolic HCl, 3 M HCl in methanol (3N), derivatization grade (GC derivatization), ampule of 20 × 1 mL

InChI

1S/ClH/h1H

InChI key

VEXZGXHMUGYJMC-UHFFFAOYSA-N

grade

derivatization grade (GC derivatization)

assay

99.9% (purity)

form

liquid

reaction suitability

reagent type: derivatization reagent
reaction type: Esterifications

packaging

ampule of 20 × 1 mL

concentration

3 M HCl in methanol (3N)

storage temp.

2-8°C

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Features and Benefits

  • Derivatization of fatty acids, particularly volatile (short chain) fatty acids.

  • Clean reaction (no side reaction) with volatile by-products.

  • Provides clean, fast, quantitative derivatization.

General description

Methanolic HCl (hydrochloric acid in methanol) is particularly useful for preparing methyl esters of volatile (short chain) fatty acids. Fatty acids are esterified by heating them with an anhydrous alcohol (e.g., methanol) in the presence of an acidic catalyst (e.g., HCl) in a sealed vessel at a high temperature for a short time. In the reaction, a fatty acid molecule and an alcohol molecule are joined, with the release of a water molecule. The derivatives can be quickly and easily recovered, quantitatively, from the reaction medium.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - Met. Corr. 1 - STOT SE 1

target_organs

Eyes,Central nervous system

Storage Class

3 - Flammable liquids

wgk

WGK 2

flash_point_f

51.8 °F - closed cup

flash_point_c

11 °C - closed cup

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
LC22019V
LC21654V
LC19167V
LC17347V
LC10109V

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Determination of limiting polyunsaturated fatty acids in Daphnia galeata using a new method to enrich food algae with single fatty acids.
Von EE.
Limnology and Oceanography, 47 (6), 1764-1773 (2002)
Nicolas Cetraro et al.
The Analyst, 144(19), 5848-5855 (2019-09-05)
The carbon-carbon double bond positions of unsaturated fatty acids can have markedly different effects on biological function and also serve as biomarkers of disease pathology, dietary history, and species identity. As such, there is great interest in developing methods for
Practical Gas Chromatography: A Comprehensive Reference.
Wilder KD and Engewald W.
Science, 613-614 (2014)
Mitochondrial Function, Part B: Mitochondrial Protein Kinases, Protein Phosphatases and Mitochondrial Diseases.
William SA and Murphy AN.
Science, 88-89 (2009)
[Fluid and electrolyte movements through the gastrointestinal membranes: hydrochloric acid formation and intestinal water transport].
D P Mertz
Klinische Wochenschrift, 45(2), 57-68 (1967-01-15)
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