11048-U
Carboxen® Carbon Adsorbent
matrix Carboxen® 569, 20-45 mesh, bottle of 500 g
Synonym(s):
carbon adsorbent, CMS, 60-80 mesh
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About This Item
product name
Carboxen® Adsorbent, matrix Carboxen® 569, 20-45 mesh, bottle of 500 g
product line
Carboxen®
Quality Level
form
powder
packaging
bottle of 500 g
technique(s)
LPLC: suitable
surface area
~485 m2/g
matrix
Carboxen® 569
matrix active group
carbon
particle size
20-45 mesh
pore size
~0.10 cm3/g macroporosity
~0.14 cm3/g mesoporosity
~0.20 cm3/g microporosity
~5-8 Å pore diameter
density
~0.61 g/mL (free fall density)
separation technique
reversed phase
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General description
Carboxen® Adsorbent is ideally used for solid-phase microextraction (SPME). It is highly efficient in extraction of small polar molecules from aqueous solution.
Carboxens are a highly engineered synthetic carbon adsorbent engineered from polymeric precursors. These particles will not plastically deform like resins or generate fines like activated carbon. These materials are shipped and stored dried. These derivatized resins bring value to a wide range of purification applications for removing both small and large molecule impurities. They find use in both gas and liquid phase purifications. Some examples include removal of homogenous catalysts from active pharmaceutical ingredients (API)s, high-risk impurities in biochemical purifications such as host cell proteins from mAbs, removal of toxic heavy metals, purification of chlorinated molecules, and removal of extractables and leachables. Tapered pores result in increased thermodynamic and kinetic properties for both adsorption and desorption. The Carboxens vary in the relative percentage of pore structures (micro, meso, and macro), surface area, and surface pH.
Application
Carboxen® 569 was used for trapping a range of replacement chlorofluorocarbons varying in boiling point from -48.4 to -9.8°C which is highly advantageous for analysis of trace gases in atmosphere.
Features and Benefits
Features and Benefits:
- Spherical
- Hard (ball pan hardness >98%)
- Stable up to 400°C
- High purity
- Easy to pack
- Stable over entire pH range
- Do not create backpressure
- High osmotic shock stability
- Tapered pore sizing (from macro- to meso- to micro-)
Other Notes
For more information, please visit: specialty Carbon Adsorbents
Legal Information
Carboxen is a registered trademark of Merck KGaA, Darmstadt, Germany
Storage Class Code
11 - Combustible Solids
WGK
nwg
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Evaluation of Carboxen carbon molecular sieves for trapping replacement chlorofluorocarbons.
O'Doherty SJ, et al.
Journal of Chromatography A, 630 (1), 265-274 (1993)
B D Page et al.
Journal of chromatography. A, 873(1), 79-94 (2000-04-11)
The headspace solid-phase microextraction (HS-SPME) efficiencies from vegetable oil of the recently available Carboxen-poly(dimethylsiloxane) (PDMS) and divinylbenzene-Carboxen-PDMS fibres were found to be much greater than those of the PDMS fibre for a number of volatile contaminants. Using these Carboxen-based fibres
Sebastien Allard et al.
Journal of chromatography. A, 1238, 15-21 (2012-04-13)
Trihalomethanes are predominantly formed during disinfection of water via reactions of the oxidant with natural organic matter. Even though chlorinated and brominated trihalomethanes are the most widespread organic contaminants in drinking water, when iodide is present in raw water iodinated
Dawn M Chapman et al.
Journal of agricultural and food chemistry, 52(17), 5431-5435 (2004-08-19)
A rapid and automated solid phase microextraction (SPME) stable isotope dilution gas chromatography/mass spectrometry (GC-MS) method for 2-methoxy-3-isobutylpyrazine (MIBP) quantification in red wine was developed. Wines with 30% (w/v) NaCl and 2-methoxy-(2)H(3)-3-isobutylpyrazine internal standard were sampled with a 2 cm
Louise Urruty et al.
Journal of agricultural and food chemistry, 50(11), 3129-3136 (2002-05-16)
To provide an efficient and running analytical tool to strawberry plant breeders who have to characterize and compare the aromatic properties of new cultivars to those already known, a HS-SPME/GC-MS analysis method has been coupled with a statistical treatment method
Articles
Synthetic CMS carbons offer tailored adsorbents for specific applications.
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
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