M4632
2-Chloro-5,5-dimethyl-1,3-cyclohexanedione
Synonym(s):
2-Chlorodimedone
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About This Item
Empirical Formula (Hill Notation):
C8H11ClO2
CAS Number:
Molecular Weight:
174.62
Beilstein:
2326749
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
Recommended Products
technique(s)
HPLC: suitable
gas chromatography (GC): suitable
mp
161-164 °C (lit.)
format
neat
storage temp.
−20°C
SMILES string
CC1(C)CC(=O)C(Cl)C(=O)C1
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Application
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Substrates
Substrate for chloroperoxidase.
Storage Class Code
13 - Non Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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K W Zuurbier et al.
Biochimica et biophysica acta, 1037(2), 140-146 (1990-02-09)
The steady-state activity of myeloperoxidase in the chlorination of monochlorodimedone at neutral pH was investigated. Using a stopped-flow spectrophotometer we were able to show that the enzymic activity at pH 7.2 rapidly declined in time. During the first 50-100 ms
D Nowak et al.
Free radical biology & medicine, 16(4), 517-522 (1994-04-01)
We tested whether Ambroxol, a drug which stimulates the release of surfactant by pneumocytes type II, may also possess antioxidant properties. To assess the reactivity of Ambroxol with reactive oxygen species, we analysed its ability to decompose hydrogen peroxide (H2O2)
P Barnett et al.
The Journal of biological chemistry, 273(36), 23381-23387 (1998-08-29)
Here we describe the isolation, purification, and basic kinetic parameters of a vanadium type chloroperoxidase from the hyphomycete fungus Embellisia didymospora. The enzyme proved to possess similar high substrate affinities, a Km of 5 microM for a bromide, 1.2 mM
E de Boer et al.
The Journal of biological chemistry, 263(25), 12326-12332 (1988-09-05)
The reaction of vanadium-bromoperoxidase from the brown alga Ascophyllum nodosum with hydrogen peroxide, bromide, and 2-chlorodimedone has been subjected to an extensive steady-state kinetic analysis. Systematic variation of pH and the concentrations of these three components demonstrate that the reaction
Tina Kirchner et al.
Archives of biochemistry and biophysics, 495(1), 21-27 (2009-12-19)
The heme-containing enzyme myeloperoxidase (MPO) accumulates at inflammatory sites and is able to catalyse one- and two-electron oxidation reactions. Here it is shown that (-)-epicatechin, which is known to have numerous beneficial health effects, in low micromolar concentration enhances the
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