76532
Geranyl pyrophosphate lithium salt
≥95.0% (TLC)
Synonym(s):
(E)-3,7-Dimethyl-2,6-octadien-1-ol trihydrogen pyrophosphate lithium salt, (E)-3,7-Dimethyl-2,6-octadien-1-yl pyrophosphate lithium salt, GPP-Li
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About This Item
Empirical Formula (Hill Notation):
C10H20O7P2 · xLi+
CAS Number:
Molecular Weight:
314.21 (free acid basis)
MDL number:
UNSPSC Code:
85151701
NACRES:
NA.25
Beilstein/REAXYS Number:
1915690
Assay:
≥95.0% (TLC)
Form:
powder
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Related Categories
Biochem/physiol Actions
Metabolite in monoterpenoid biosynthesis, substrate for monoterpene synthases.
Packaging
Bottomless glass bottle. Contents are inside inserted fused cone.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Fu-Lien Hsieh et al.
Journal of molecular biology, 404(5), 859-873 (2010-10-23)
Isoprenoids, most of them synthesized by prenyltransferases (PTSs), are a class of important biologically active compounds with diverse functions. The mint geranyl pyrophosphate synthase (GPPS) is a heterotetramer composed of two LSU·SSU (large/small subunit) dimers. In addition to C(10)-GPP, the
Giuseppe Tringali et al.
Neuroscience letters, 354(2), 107-110 (2003-12-31)
Statins were recently shown to possess anti-inflammatory activities, which might be responsible for their favourable effects in cardiovascular or CNS disorders independently from the inhibition of hydroxy-methyl-glutaryl CoA reductase. Here we investigated the effects of the statins lovastatin and mevastatin
Annie P-C Chen et al.
The Biochemical journal, 386(Pt 1), 169-176 (2004-09-28)
UPPS (undecaprenyl pyrophosphate synthase) catalyses consecutive condensation reactions of FPP (farnesyl pyrophosphate) with eight isopentenyl pyrophosphates to generate C55 UPP, which serves as a lipid carrier for bacterial peptidoglycan biosynthesis. We reported the co-crystal structure of Escherichia coli UPPS in
Axel Schmidt et al.
Plant physiology, 152(2), 639-655 (2009-11-27)
The conifer Picea abies (Norway spruce) defends itself against herbivores and pathogens with a terpenoid-based oleoresin composed chiefly of monoterpenes (C(10)) and diterpenes (C(20)). An important group of enzymes in oleoresin biosynthesis are the short-chain isoprenyl diphosphate synthases that produce
Orapin Ariyawutthiphan et al.
Acta crystallographica. Section F, Structural biology and crystallization communications, 67(Pt 3), 417-420 (2011-03-12)
The biosynthetic pathway of the off-flavour terpenoid alcohol 2-methylisoborneol (2-MIB) requires geranyl pyrophosphate methyltransferase (GPPMT) to methylate GPP before the cyclization reaction. GPPMT is the first example of an S-adenosyl-L-methionine-dependent methyltransferase that acts on general intermediates such as geranyl pyrophosphate
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