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69769

Sigma-Aldrich

Microperoxidase disodium salt from horse heart

≥85% (HPCE)

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Synonym(s):
H-11-PT, Haeme undecapeptide, MP-11
Empirical Formula (Hill Notation):
C84H114FeN20Na2O21S2
CAS Number:
104684-94-2
Molecular Weight:
1905.88
MDL number:
MFCD00168071
UNSPSC Code:
12352108
PubChem Substance ID:
329761945
NACRES:
NA.32

Assay

≥85% (HPCE)

form

powder

impurities

peroxidase activity
≤10% water

solubility

H2O: 10 mg/mL, clear, dark red-brown

storage temp.

−20°C

SMILES string

O.O.O.O.[Na+].[Na+].CC(C)[C@H](N)C(=O)N[C@@H](CCC(O)=O)C(=O)N[C@@H](CCCCN)C(=O)N[C@H]1CSSC(C)c2c(C)c3nc2nc4c(C)c(CCC([O-])=O)c5nc6nc(nc7c(C)c(C(C)SSC[C@H](NC(=O)[C@H](CCC(N)=O)NC(=O)[C@H](C)NC1=O)C(=O)N[C@@H](Cc8c[nH]cn8)C(=O)N[C@@H]([C@@H](C)O)C(=O)N[C@@H](C(C)C)C(=O)N[C@@H](CCC(O)=O)C(O)=O)c(n3)n7[Fe]n45)c(C)c6CCC([O-])=O

InChI

1S/C80H113N23O22S4.Fe.2Na.4H2O/c1-32(2)59(83)77(121)89-47(19-24-55(110)111)72(116)88-45(15-13-14-26-81)71(115)92-50-29-126-128-41(12)58-37(8)65-101-68(58)99-63-35(6)44(17-23-54(108)109)67(98-63)103-66-43(16-22-53(106)107)34(5)62(97-66)96-64-36(7)57(69(100-64)102-65)40(11)129-127-30-51(93-73(117)46(18-21-52(82)105)87-70(114)38(9)86-75(50)119)76(120)91-49(27-42-28-84-31-85-42)74(118)95-61(39(10)104)79(123)94-60(33(3)4)78(122)90-48(80(124)125)20-25-56(112)113;;;;;;;/h28,31-33,38-41,45-51,59-61,104H,13-27,29-30,81,83H2,1-12H3,(H20,82,84,85,86,87,88,89,90,91,92,93,94,95,96,97,98,99,100,101,102,103,105,106,107,108,109,110,111,112,113,114,115,116,117,118,119,120,121,122,123,124,125);;;;4*1H2/q;+2;2*+1;;;;/p-4/t38-,39+,40?,41?,45-,46-,47-,48-,49-,50-,51-,59-,60-,61-;;;;;;;/m0......./s1

InChI key

HARTZTRJJQAYAK-FJHAOVHCSA-J

Antibody Adsorbant

Val-Glu-Lys-(Cys-Ala-Gln-Cys)Heme-His-Thr-Val-Glu

Preparation Note

prepared by enzymatic degradation of horse heart cytochrome c

Other Notes

Cationic heme undecapeptide as stain for detecting glycosaminoglycans on cellulose acetate; Kinetic study of pH-dependent properties
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WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

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M T Wilson et al.
European journal of biochemistry, 77(1), 193-199 (1977-07-01)
The ferric form of the haem undecapeptide, derived from horse cytochrome c by peptic digestion, undergoes at least three pH-induced transitions with pK values of 3.4, 5.8 and 7.6. Temperature-jump experiments suggest that the first of these is due to
N Ghinea
Analytical biochemistry, 155(1), 78-82 (1986-05-15)
A rapid and sensitive method has been developed for detecting glycosaminoglycans on cellulose acetate strips. The method is based on the electrostatic interactions between glycosaminoglycans and cationic heme undecapeptide. The complexes are identified by peroxidatic reaction using 3,3'-diaminobenzidine as H2

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