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60489

Sigma-Aldrich

Potassium peroxodisulfate

puriss. p.a., ACS reagent, ≥99.0% (RT)

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Synonym(s):
Potassium persulfate
Linear Formula:
K2S2O8
CAS Number:
7727-21-1
Molecular Weight:
270.32
EC Number:
231-781-8
MDL number:
MFCD00011386
UNSPSC Code:
12352300
PubChem Substance ID:
329759024
NACRES:
NA.21

grade

ACS reagent
puriss. p.a.

Quality Level

200

Assay

≥99.0% (RT)

form

powder or crystals

impurities

≤0.001% total nitrogen (N)

pH

2.5-4.5 (25 °C, 27 g/L)

anion traces

chloride (Cl-): ≤10 mg/kg

cation traces

Ag: ≤5 mg/kg
Al: ≤5 mg/kg
Ba: ≤5 mg/kg
Bi: ≤5 mg/kg
Ca: ≤50 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cr: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤5 mg/kg
Li: ≤5 mg/kg
Mg: ≤100 mg/kg
Mn: ≤1 mg/kg
Mo: ≤5 mg/kg
Na: ≤200 mg/kg
Ni: ≤5 mg/kg
Pb: ≤5 mg/kg
Sr: ≤5 mg/kg
Tl: ≤5 mg/kg
Zn: ≤5 mg/kg

application(s)

forensics and toxicology

SMILES string

[K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O

InChI

1S/2K.H2O8S2/c;;1-9(2,3)7-8-10(4,5)6/h;;(H,1,2,3)(H,4,5,6)/q2*+1;/p-2

InChI key

USHAGKDGDHPEEY-UHFFFAOYSA-L

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General description

Potassium peroxodisulfate is also known as potassium persulfate (K2S2O8). It is commonly used as an oxidizing agent and polymerization initiator in organic synthesis.

Application

Potassium peroxodisulfate can be used as:      
  • A polymerization initiator in the synthesis of polyacrylamide via radical polymerization of acrylamide.      
  • An oxidizing agent in the photochemical oxidation of atrazine aqueous solution.

K2S2O8 can also be used in the following process:      
  • K2S2O8-AgSCF3 catalytic system is used in the direct trifluoromethylthiolation of unactivated C(sp3)-H bonds under mild conditions. Usage of K2S2O8 in this process plays an important role in the activation of the C-H bond and the oxidation of AgSCF3.
  • K2S2O8-FeCl3 is used for the thiocyanation of 2H-indazoles using ammonium thiocyanate as a thiocyanating agent.

Other Notes

Oxidizing agent for decomposition by fusion

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Ox. Sol. 3 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

危险化学品

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Z. Sulcek et al.
Methods of Decomposition in Inorganic Analysis (1989)
R. Bock
Aufschlussmethoden der anorg. & org. Chemie (1972)
Harriet Mörtstedt et al.
Rapid communications in mass spectrometry : RCM, 25(2), 327-340 (2010-12-31)
Oxidative stress has been suggested as an underlying mechanism of many human diseases. However, definitive evidence for this association has not been presented due to different shortcomings of the methods used to measure biomarkers of oxidative stress. Persulfates are oxidizing
Zhiyong Yang et al.
The Journal of organic chemistry, 77(16), 7086-7091 (2012-07-28)
Nontransition metal-catalyzed synthesis of 2-aryl benzothiazoles was achieved through K(2)S(2)O(8)-mediated oxidative condensation of benzothiazoles with aryl aldehydes. The same transformation can also be effected when the aryl aldehydes were replaced with phenylglyoxylic acids.
Monica H Kåredal et al.
Journal of proteome research, 9(11), 5620-5628 (2010-09-08)
Hairdressers are frequently exposed to bleaching powder containing persulfates, a group of compounds that may induce hypersensitivity in the airways. The mechanism causing this reaction is not clear. The aim of this study was to identify changes in the nasal
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