26420
Chloro(2,2′:6′,2″-terpyridine)platinum(II) chloride dihydrate
≥99.0% (AAS)
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Synonym(s):
Dichloro(2,2′:6′,2′′-terpyridine)platinum(II) dihydrate
Empirical Formula (Hill Notation):
C15H11Cl2N3Pt · 2H2O
CAS Number:
Molecular Weight:
535.28
MDL number:
UNSPSC Code:
12171500
PubChem Substance ID:
NACRES:
NA.32
Recommended Products
Quality Level
Assay
≥99.0% (AAS)
SMILES string
O.O.Cl[Pt]Cl.c1ccc(nc1)-c2cccc(n2)-c3ccccn3
InChI
1S/C15H11N3.2ClH.2H2O.Pt/c1-3-10-16-12(6-1)14-8-5-9-15(18-14)13-7-2-4-11-17-13;;;;;/h1-11H;2*1H;2*1H2;/q;;;;;+2/p-2
InChI key
WEBUYGBVKZYTMT-UHFFFAOYSA-L
Other Notes
An intercalator of helical and double stranded DNA; Spectroscopic tag for proteins. Selective covalent labeling of histidine in cytochromes c; Intercalation
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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S. J. Lippard
Accounts of Chemical Research, 11, 211-211 (1987)
K W Jennette et al.
Proceedings of the National Academy of Sciences of the United States of America, 71(10), 3839-3843 (1974-10-01)
The red, cationic complex 2-hydroxy-ethanethiolato(2,2',2''-terpyridine)platinum(II), [(terpy)-Pt(SCH(2)CH(2)OH)](+), binds strongly to DNA by a mechanism involving intercalation. By means of fluorescence spectroscopy, the platinum complex was shown to inhibit competitively the binding of the intercalating dye ethidium bromide to calf thymus DNA.
E.M.A. Ratilla et al.
Journal of the American Chemical Society, 109, 4592-4592 (1987)
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