12271
2-Keto-3-deoxy-D-gluconic acid lithium salt
≥95% (TLC)
Synonym(s):
3-Deoxy-D-erythro-2-hexulosonic acid lithium salt, KDG, Lithium 2-keto-3-deoxy-D-gluconate
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About This Item
Empirical Formula (Hill Notation):
C6H10O6 · xLi+
CAS Number:
Molecular Weight:
178.14 (free acid basis)
UNSPSC Code:
12352204
NACRES:
NA.32
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Assay
≥95% (TLC)
form
powder or crystals
storage temp.
−20°C
InChI
1S/C6H10O6/c7-2-5(10)3(8)1-4(9)6(11)12/h3,5,7-8,10H,1-2H2,(H,11,12)/t3-,5+/m0/s1
InChI key
WPAMZTWLKIDIOP-WVZVXSGGSA-N
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Biochem/physiol Actions
Metabolite in the pentose phosphate pathway, which generates NADPH and pentoses; KDG is an intermediate in the metabolism of glucose and gluconic acid in some pseudomonas strains, of uronic acids in E. coli, and also an important metabolite in the degradation of polygalacturonates in Erwinia chrysanthemi.
Packaging
Bottomless glass bottle. Contents are inside inserted fused cone.
Caution
Hygroscopic.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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G Condemine et al.
Journal of bacteriology, 165(3), 937-941 (1986-03-01)
Mutants of Erwinia chrysanthemi impaired in pectin degradation were isolated by chemical and Mu d(Ap lac) insertion mutagenesis. A mutation in the kduD gene coding for 2-keto-3-deoxygluconate oxidoreductase prevented the growth of the bacteria on polygalacturonate as the sole carbon
Uronic acid metabolism in bacteria. IV. Purification and properties of 2-keto-3-deoxy-D-gluconokinase in Escherichia coli.
M A CYNKIN et al.
The Journal of biological chemistry, 235, 1576-1579 (1960-06-01)
Carbohydrate metabolism by Pseudomonas fluorescens. III. Purification and properties of a 6-phosphogluconate dehydrase.
R KOVACHEVICH et al.
The Journal of biological chemistry, 213(2), 745-756 (1955-04-01)
Uronic acid metabolism in bacteria. I. Purification and properties of uronic acid isomerase in Escherichia coli.
G ASHWELL et al.
The Journal of biological chemistry, 235, 1559-1565 (1960-06-01)
A new pathway of uronic acid metabolism.
A ASHWELL et al.
Biochimica et biophysica acta, 30(1), 186-187 (1958-10-01)
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