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Key Documents

Safety Information

D56802

Sigma-Aldrich

1,2-Dichlorobenzene

ReagentPlus®, 99%

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About This Item

Empirical Formula (Hill Notation):
C6H4Cl2
CAS Number:
Molecular Weight:
147.00
Beilstein:
606078
EC Number:
MDL number:
UNSPSC Code:
12191501
PubChem Substance ID:
NACRES:
NA.04
Assay:
99%
bp:
178-180 °C (lit.)
vapor pressure:
1.2 mmHg ( 20 °C)
1.6 mmHg ( 35 °C)

vapor density

5.1 (vs air)

Quality Level

vapor pressure

1.2 mmHg ( 20 °C)
1.6 mmHg ( 35 °C)

product line

ReagentPlus®

Assay

99%

form

liquid

autoignition temp.

1198 °F

expl. lim.

9.2 %

refractive index

n20/D 1.551 (lit.)

bp

178-180 °C (lit.)

mp

−18-−17 °C (lit.)

density

1.306 g/mL at 25 °C (lit.)

SMILES string

Clc1ccccc1Cl

InChI

1S/C6H4Cl2/c7-5-3-1-2-4-6(5)8/h1-4H

InChI key

RFFLAFLAYFXFSW-UHFFFAOYSA-N

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Application

1,2-Dichlorobenzene can be used as a solvent:
  • In the Wohl-Ziegler bromination of methoxyimino-o-tolyl-acetic acid methyl esters.
  • To synthesize poly(butyleneterephthalate) copolyesters via polycondensation.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

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Pictograms

Exclamation markEnvironment

Signal Word

Warning

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1B - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 2

Flash Point(F)

150.8 °F - closed cup

Flash Point(C)

66.0 °C - closed cup

Regulatory Information

危险化学品

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Synthesis and characterization of poly (butylene terephthalate) copolyesters derived from threitol
Ittobane N, et al.
Polymer Composites, 29, S817-S825 (2021)
Benzylic Brominations with N-Bromosuccinimide in 1, 2-Dichlorobenzene: Effective Preparation of (2-Bromomethyl-phenyl)-Methoxyiminoacetic Acid Methyl Ester
Lee S, et al.
Clean Technologies and Environmental Policy, 22, 269-273 (2016)
Ivan Guryanov et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 15(46), 12837-12845 (2009-10-23)
The effect of microwave (MW) irradiation and ionic liquids (IL) on the cycloaddition of azomethine ylides to [60]fullerene has been investigated by screening the reaction protocol with regard to the IL medium composition, the applied MW power, and the simultaneous
Eric Vejerano et al.
Environmental science & technology, 45(2), 589-594 (2010-12-09)
Previous studies have shown environmentally persistent free radicals (EPFRs) form when chlorine- and hydroxy-substituted benzenes chemisorb on Cu(II)O-containing surfaces under postcombustion conditions. This paper reports the formation of EPFRs on silica particles containing 5% Fe(III)(2)O(3). The EPFRs are formed by
Bimalendu Adhikari et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(41), 11488-11496 (2011-09-29)
The N-terminally pyrene-conjugated oligopeptide, Py-Phe-Phe-Ala-OMe, (Py=pyrene 1-butyryl acyl) forms transparent, stable, supramolecular fluorescent organogels in various organic solvents. One of these organogels was thoroughly studied using various techniques including transmission electron microscopy (TEM), field-emission scanning electron microscopy (FESEM), atomic force

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