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695092

Sigma-Aldrich

Acetic acid

glacial, ACS reagent, ≥99.7%

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Synonym(s):
Glacial acetic acid
Linear Formula:
CH3CO2H
CAS Number:
64-19-7
Molecular Weight:
60.05
Beilstein:
506007
EC Number:
200-580-7
MDL number:
MFCD00036152
UNSPSC Code:
12352106
PubChem Substance ID:
329761715
NACRES:
NA.21

grade

ACS reagent

Quality Level

200

vapor density

2.07 (vs air)

vapor pressure

11.4 mmHg ( 20 °C)

Assay

≥99.7%

form

liquid

autoignition temp.

800 °F

expl. lim.

16 %, 92 °F
4 %, 59 °F

technique(s)

mass spectrometry (MS): suitable

impurities

Cr2O72- reducers, passes test
 MnO4- reducers, passes test
≤0.0004 meq/g Titr. base
≤0.01% acetic anhydride

evapn. residue

≤0.001%

color

APHA: ≤10

refractive index

n20/D 1.371 (lit.)

pH

2.5 (20 °C, 50 g/L)

bp

117-118 °C (lit.)

mp

16.2 °C (lit.)

density

1.049 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤1 ppm
sulfate (SO42-): ≤1 ppm

cation traces

Fe: ≤0.2 ppm
heavy metals: ≤0.5 ppm (by ICP)

SMILES string

CC(O)=O

InChI

1S/C2H4O2/c1-2(3)4/h1H3,(H,3,4)

InChI key

QTBSBXVTEAMEQO-UHFFFAOYSA-N

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General description

Acetic acid is an organic carboxylic acid. It is a pungent smelling hygroscopic liquid. Glacial acetic acid is the anhydrous acetic acid. It forms dimers linked by hydrogen bonds in solution and gaseous commonly referred as phases. It is weakly acidic in nature.

Application

Acetic acid is widely employed as solvent for various oxidation reactions. It may be used in the analysis of synthetic peptides by electron transfer dissociation (ETD) tandem mass spectrometry (MS/MS). It may be used in the preparation of peroxyacetic acid (disinfectant), via reaction with perhydrol (30% hydrogen peroxide).

Other Notes

4L and 4X4L are packaged in poly bottles

Pictograms

FlameCorrosion
GHS02,GHS05

Signal Word

Danger

Hazard Statements

H226,H314

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A

WGK

WGK 1

Regulatory Information

危险化学品

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John E P Syka et al.
Proceedings of the National Academy of Sciences of the United States of America, 101(26), 9528-9533 (2004-06-24)
Peptide sequence analysis using a combination of gas-phase ion/ion chemistry and tandem mass spectrometry (MS/MS) is demonstrated. Singly charged anthracene anions transfer an electron to multiply protonated peptides in a radio frequency quadrupole linear ion trap (QLT) and induce fragmentation
Eagleson M.
Concise Encyclopedia Chemistry, 5-5 (1994)
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The Journal of clinical investigation, 124(7), 3230-3240 (2014-06-18)
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Katharine Trenholme et al.
Antimicrobial agents and chemotherapy, 58(7), 3666-3678 (2014-04-16)
Therapies to prevent transmission of malaria parasites to the mosquito vector are a vital part of the global malaria elimination agenda. Primaquine is currently the only drug with such activity; however, its use is limited by side effects. The development
Ken Ye et al.
PloS one, 9(6), e99410-e99410 (2014-06-12)
Infrapatellar fat pad adipose stem cells (IPFP-ASCs) have been shown to harbor chondrogenic potential. When combined with 3D polymeric structures, the stem cells provide a source of stem cells to engineer 3D tissues for cartilage repair. In this study, we
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