342793
Magnesium oxide
≥99% trace metals basis, -325 mesh
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About This Item
Linear Formula:
MgO
CAS Number:
Molecular Weight:
40.30
EC Number:
MDL number:
UNSPSC Code:
12352303
PubChem Substance ID:
NACRES:
NA.21
Quality Level
Assay
≥99% trace metals basis
form
powder
reaction suitability
reagent type: catalyst
core: magnesium
loss
10% loss on ignition, 1000°C (absorbed H2O and CO2)
particle size
-325 mesh
mp
2852 °C (lit.)
SMILES string
O=[Mg]
InChI
1S/Mg.O
InChI key
CPLXHLVBOLITMK-UHFFFAOYSA-N
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General description
Magnesium oxide is a mild basic reagent used in acylations, alkylations, oxidations, reductions, formation of heterocycles, ring-opening of tertiary amines, nitration of aromatic acetals, hydrohalogenation, dehydrohalogenation, carbonylation of organomercurials, and serves as a leaving group to form alkenes.
Application
Magnesium oxide can be used as a catalyst in the:
- Dehydrogenation of n-octane to synthesize octenes.
- Solvent-free Knoevenagel condensation of aromatic aldehydes and ethyl cyanoacetate to synthesize electrophilic olefins.
Analysis Note
Purity based on metallic impurity content.
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Certificates of Analysis (COA)
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Effect of different catalyst supports on the (n, m) selective growth of single-walled carbon nanotube from Co-Mo catalyst.
Wang B, et al.
J. Mater. Sci., 44(12), 3285-3295 (2009)
Synthesis of ethylene and ethane by partial oxidation of methane over lithium-doped magnesium oxide.
Ito T and Lunsford JH.
Nature, 721-722 (1985)
Eagleson M.
Concise Encyclopedia Chemistry, 495-495 (1994)
Magnesium oxide-catalysed reaction of carbon dioxide with an epoxide with retention of stereochemistry.
Yano T, et al.
Chemical Communications (Cambridge, England), 12, 1129-1130 (1997)
Magdalena Maciejewska et al.
Journal of chromatography. A, 1257, 141-148 (2012-08-22)
Inverse gas chromatography (IGC) was applied at infinite dilution to evaluate the surface properties of calcium and magnesium oxide nanoparticles and the effect of surface grafted unsaturated carboxylic acid on the nanopowder donor-acceptor characteristics. The dispersive components (γ(s)(D)) of the
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