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31462

Sigma-Aldrich

Nickel(II) chloride hexahydrate

puriss. p.a., ≥98%

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Linear Formula:
NiCl2 · 6H2O
CAS Number:
7791-20-0
Molecular Weight:
237.69
MDL number:
MFCD00149809
UNSPSC Code:
12352300
PubChem Substance ID:
329753776
NACRES:
NA.21

grade

puriss. p.a.

Quality Level

200

Assay

≥98%

form

powder or crystals

reaction suitability

reagent type: catalyst
core: nickel

pH

4-7 (20 °C, 5%)

anion traces

sulfate (SO42-): ≤50 mg/kg

cation traces

Ca: ≤50 mg/kg
Cd: ≤10 mg/kg
Co: ≤100 mg/kg
Cu: ≤10 mg/kg
Fe: ≤20 mg/kg
Mg: ≤10 mg/kg
Na: ≤50 mg/kg
Pb: ≤10 mg/kg
Zn: ≤10 mg/kg

storage temp.

room temp

SMILES string

[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].Cl[Ni]Cl

InChI

1S/2ClH.Ni.6H2O/h2*1H;;6*1H2/q;;+2;;;;;;/p-2

InChI key

LAIZPRYFQUWUBN-UHFFFAOYSA-L

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General description

Nickel(II) chloride hexahydrate is a hydrated nickel salt. Its crystals were monoclinic and structure was investigated by X-ray single crystal method.

Application

Nickel(II) chloride hexahydrate may be employed as a catalyst in the high yield synthesis of tetra-substituted pyrrole derivatives. It may be used for the conversion of tetrahydropyranyl (THP) and tert-butyldimethylsilyl (TBS) ethers to the corresponding hydroxyl compounds.

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A Inhalation - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 Inhalation

Target Organs

Lungs

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

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The Crystal Structure of Nickel Chloride Hexahydrate, NiCl2.6H2O.
Mizuno J.
Journal of the Physical Society of Japan, 16(8), 1571-1580 (1961)
Synthesis of tetra-substituted pyrroles, a potential phosphodiesterase 4B inhibitor, through nickel (II) chloride hexahydrate catalyzed one-pot four-component reaction.
Khan AT, et al.
Tetrahedron Letters, 53(32), 4145-4150 (2012)
A catalytic amount of nickel (II) chloride hexahydrate and 1, 2-ethanedithiol is a good combination for the cleavage of tetrahydropyranyl (THP) and tert-butyldimethylsilyl (TBS) ethers.
Khan AT, et al.
Tetrahedron Letters, 45(52), 9617-9621 (2004)
Terran E Bergdale et al.
Journal of biotechnology, 161(3), 181-189 (2012-07-14)
Microbiologically induced calcium carbonate precipitation (MICCP) is a naturally occurring biological process that has shown its potential in remediation of a wide range of structural damages including concrete cracks. In this study, genetically engineered microorganisms, capable of producing extracellular polymeric
Ritu Tyagi et al.
Journal of applied toxicology : JAT, 33(2), 134-141 (2011-09-20)
Heavy metals are known for their associated nephrotoxicity and nickel is no exception. An integrated metabonomic approach, based on high-resolution (1) H NMR spectroscopy, was applied to determine the acute biochemical effects of NiCl(2) on the renal tissues of rats.
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