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Merck
CN

31277

Cobalt(II) chloride hexahydrate

puriss. p.a., ACS reagent, reag. Ph. Eur., 98-102%

Synonym(s):

Cobaltous chloride hexahydrate

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About This Item

Linear Formula:
CoCl2 · 6H2O
CAS Number:
7791-13-1
Molecular Weight:
237.93
NACRES:
NB.24
PubChem Substance ID:
329753717
UNSPSC Code:
12352302
EC Number:
231-589-4
MDL number:
MFCD00149652
Assay:
98-102%
Form:
solid

Key Documents

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Product Name

Cobalt(II) chloride hexahydrate, puriss. p.a., ACS reagent, reag. Ph. Eur., 98-102%

InChI key

GFHNAMRJFCEERV-UHFFFAOYSA-L

InChI

1S/2ClH.Co.6H2O/h2*1H;;6*1H2/q;;+2;;;;;;/p-2

SMILES string

O.O.O.O.O.O.Cl[Co]Cl

grade

ACS reagent
puriss. p.a.

agency

reag. Ph. Eur.

vapor pressure

40 mmHg ( 0 °C)

assay

98-102%

form

solid

impurities

≤0.01% water-insoluble matter

anion traces

nitrate (NO3-): ≤100 mg/kg
sulfate (SO42-): ≤50 mg/kg

cation traces

Ca: ≤50 mg/kg
Cu: ≤20 mg/kg
Fe: ≤50 mg/kg
K: ≤50 mg/kg
Mg: ≤10 mg/kg
Mn: ≤50 mg/kg
Na: ≤100 mg/kg
Ni: ≤500 mg/kg
Pb: ≤5 mg/kg
Zn: ≤25 mg/kg

Quality Level

200

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Application

Cobalt(II) chloride hexahydrate can be used as a catalyst:      
  • To convert various aldoximes into corresponding nitriles in the presence of an inorganic base.      
  • To prepare organic-inorganic polyvinylidene fluoride nanofiber composites (PVDF/CoCl2) for the production of pure hydrogen production from NaBH4.

It can also be used as a cobalt precursor to synthesize nickel-cobalt-based binary metal phosphide (NiCoP) hollow spheres, which are used for electrocatalysis and energy storage (supercapacitor) applications.

General description

Cobalt(II) chloride hexahydrate is a hydrated form of cobalt chloride. It is used as a catalyst for various organic reactions such as acetylation and tosylation of alcohols, chemoselective reduction of carboxylic esters, and condensation reactions.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Eye Dam. 1 - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
MKCZ5648
MKCX8165
MKCW2236
MKCS1059
MKCT4607

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Biochemical and biophysical research communications, 450(1), 476-481 (2014-06-14)
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Senthilguru Kulanthaivel et al.
Materials science & engineering. C, Materials for biological applications, 58, 648-658 (2015-10-20)
The present study delineates the synthesis and characterization of cobalt doped proangiogenic-osteogenic hydroxyapatite. Hydroxyapatite samples, doped with varying concentrations of bivalent cobalt (Co(2+)) were prepared by the ammoniacal precipitation method and the extent of doping was measured by ICP-OES. The
Juhui Ko et al.
Journal of hazardous materials, 285, 11-17 (2014-12-03)
Aflatoxin B1 (AFB1) is a well-known carcinogenic contaminant in foods. It is classified as an extremely hazardous compound because of its potential toxicity to the human nervous system. AFB1 has also been extensively used as a biochemical marker to evaluate
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