310700
Manganese(IV) oxide
10 μm, reagent grade, ≥90%
Synonym(s):
Manganese dioxide
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About This Item
Empirical Formula (Hill Notation):
MnO2
CAS Number:
Molecular Weight:
86.94
EC Number:
MDL number:
UNSPSC Code:
12352303
PubChem Substance ID:
NACRES:
NA.55
grade
reagent grade
Quality Level
Assay
≥90%
form
powder
particle size
10 μm
mp
535 °C (dec.) (lit.)
SMILES string
O=[Mn]=O
InChI
1S/Mn.2O
InChI key
NUJOXMJBOLGQSY-UHFFFAOYSA-N
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General description
Manganese(IV) oxide is an oxidizing reagent that can be used for the oxidation of propargylic alcohols, benzylic or heterocyclic alcohols, saturated alcohols, 1,2-diols, allylic alcohols to α, β-ethylenic aldehydes or ketones, and amines to aldehydes, imines, amides, and diazo compounds. It can also be used for the conversion of allylic alcohols to α, β-ethylenic esters or amides, hydration of nitriles to amides, dehydrogenation and aromatization reactions.
Application
- High-oxidation-state 3d metal complexes: Explores the catalytic properties of manganese(IV) oxide within high-oxidation-state complexes for advanced organic synthesis, demonstrating its critical role in accelerating chemical reactions and enhancing yield efficiencies, beneficial for pharmaceutical and chemical industries (Cheng J et al., 2018).
- Synthesis and properties of manganese complexes: Details the synthesis of new manganese complexes that demonstrate unique redox properties, useful for understanding electron transfer processes in various chemical and environmental contexts (Baffert C et al., 2002).
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - STOT RE 2 Inhalation
Target Organs
Brain
WGK
WGK 2
Flash Point(F)
does not flash
Flash Point(C)
does not flash
Certificates of Analysis (COA)
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Manganese dioxide
Cahiez G, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis (2001)
Xing Liu et al.
The Analyst, 137(19), 4552-4558 (2012-08-18)
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Advanced materials (Deerfield Beach, Fla.), 24(37), 5071-5076 (2012-07-05)
Y Wang et al.
Journal of colloid and interface science, 380(1), 8-15 (2012-06-02)
Bio-inspired chemical approach has been developed for the surface modification and electrophoretic deposition of manganese dioxide and zirconia nanoparticles, prepared by chemical precipitation methods. Caffeic acid, trans-cinnamic acid, p-coumaric acid, and 2,4-dihydroxycinnamic acid were investigated for the surface modification of
Wen-Hui Kuan et al.
Journal of hazardous materials, 239-240, 152-159 (2012-09-25)
This study examined the reaction of methylene blue (MB) with tunneled manganese oxide pyrolusite regarding pH and reaction time. MB was cleaved through N-demethylation, in which reaction azure B (AB), azure A (AA), azure C (AC), and thionin (TH) were
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