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Merck
CN

234125

Iron(III) ferrocyanide

Synonym(s):

Ferric ferrocyanide, Ferrihexacyanoferrate, Ferrocin, Prussian blue

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About This Item

Linear Formula:
Fe4[Fe(CN)6]3
CAS Number:
Molecular Weight:
859.23
NACRES:
NA.55
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
237-875-5
MDL number:
Form:
powder
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InChI key

DNMNDNSFJMUUFM-UHFFFAOYSA-N

InChI

1S/18CN.7Fe/c18*1-2;;;;;;;/q;;;;;;;;;;;;;;;;;;3*-4;4*+3

SMILES string

[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N.N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N.N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N

form

powder

concentration

≥30% (ICP)

λmax

694 nm

Quality Level

Related Categories

Application

Iron(III) ferrocyanidecyclic can be used as:
  • A catalyst to synthesize cyclic carbonates by reaction between carbon dioxide and epoxides.
  • A precursor to prepare Fe-Fe3C nanoparticle encapsulated N-doped graphene layers via pyrolysis.

Storage Class

11 - Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


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Chen Zhai et al.
Biosensors & bioelectronics, 42, 124-130 (2012-12-04)
In this paper, chitosan-prussian blue-multiwall carbon nanotubes-hollow gold nanospheres (Chit-PB-MWNTs-HGNs) film was fabricated onto the gold electrode surface by one-step electrodeposition method; and then acetylcholinesterase (AChE) and Nafion were modified onto the film to prepare an AChE biosensor. Incorporating MWNTs
Guanglei Fu et al.
Chemical communications (Cambridge, England), 48(94), 11567-11569 (2012-10-24)
Herein, prussian blue nanoparticles, an ancient dye, were explored as a new generation of near-infrared laser-driven photothermal ablation agents for cancer therapy alternative to traditional agents due to their good photothermal efficiency and high photothermal stability but low cost and
Prussian blue as a single precursor for synthesis of Fe/Fe3C encapsulated N-doped graphitic nanostructures as bi-functional catalysts
Barman BK and Nanda KK
Green Chemistry, 18(2), 427-432 (2016)
High conversion of CO2 into cyclic carbonates under solvent-free and ambient pressure conditions by a Fe-cyanide complex
Jiang P, et al.
New. J. Chem., 43(44), 17211-17219 (2019)
Hassina Baraki et al.
PloS one, 7(12), e51770-e51770 (2012-12-14)
We sought to detect an acute soft tissue infection in rats by magnetic resonance imaging (MRI) using granulocytes, previously labeled with superparamagnetic particles of iron oxide (SPIO). Parasternal infection was induced by subcutaneous inoculation of Staphylococcus aureus suspension in rats.

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