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217557

Sigma-Aldrich

Copper(II) acetate monohydrate

greener alternative

ACS reagent, ≥98%

Synonym(s):

Cupric acetate monohydrate

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About This Item

Linear Formula:
Cu(CO2CH3)2 · H2O
CAS Number:
6046-93-1
Molecular Weight:
199.65
Beilstein:
3730548
EC Number:
205-553-3
MDL number:
MFCD00149570
UNSPSC Code:
12352103
PubChem Substance ID:
329752200
NACRES:
NB.24

grade

ACS reagent

Quality Level

200

vapor density

6.8 (vs air)

Assay

≥98%
98.0-102.0% (ACS specification)

form

crystalline powder
lumps and powder

reaction suitability

reagent type: catalyst
core: copper

greener alternative product characteristics

Catalysis
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sustainability

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impurities

≤0.01% insolubles

pH

5.2-5.5 (20 °C, 20 g/L)

anion traces

chloride (Cl-): ≤0.003%
sulfate (SO42-): ≤0.01%

cation traces

Ca: ≤0.005%
Fe: ≤0.002%
K: ≤0.01%
Na: ≤0.05%
Ni: ≤0.01%

greener alternative category

SMILES string

O.CC(=O)O[Cu]OC(C)=O

InChI

1S/2C2H4O2.Cu.H2O/c2*1-2(3)4;;/h2*1H3,(H,3,4);;1H2/q;;+2;/p-2

InChI key

NWFNSTOSIVLCJA-UHFFFAOYSA-L

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis. Click here for more information.

Application

Catalyst for activation of alcohols as greener alkylating reagents

Copper-Catalyzed Aerobic Oxidation of Amines to Imines under Neat Conditions with Low Catalyst Loading

Signal Word

Danger

Hazard Statements

H302,H314,H410

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

does not flash

Flash Point(C)

does not flash

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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The kinetics of thermal dehydration of copper (II) acetate monohydrate in air.
Zhang K, et al.
Thermochimica Acta, 437(1), 145-149 (2005)
Dinuclear copper (II) acetate monohydrate: a redetermination of the structure by neutron-diffraction analysis.
Brown GM and Chidambaram R.
Acta Crystallographica Section B, Structural Science, 29(11), 2393-2403 (1973)
F Heidenau et al.
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