161527
Sodium hydrosulfide hydrate
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About This Item
Linear Formula:
NaSH·xH2O
CAS Number:
Molecular Weight:
56.06 (anhydrous basis)
NACRES:
NA.55
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
Form:
chips, flakes
Quality Level
form
chips, flakes
concentration
≥60% (by Na2S2O3, titration)
mp
52-54 °C (lit.)
SMILES string
[Na]S.[H]O[H]
InChI
1S/Na.H2O.H2S/h;2*1H2/q+1;;/p-1
InChI key
ZNKXTIAQRUWLRL-UHFFFAOYSA-M
General description
Sodium hydrosulfide hydrate is a hydrated inorganic salt of sodium. It participates in the synthesis of (E)-2-cyano-2-(thiazolidin-2-ylidene)ethanethioamide.
Application
It may be used as a sulfur nucleophile to induce the C-S bond formation in α,β-dichloro vinyl ketones to form 5- to 8-membered cyclic thioethers.
Sodium hydrosulfide hydrate may be used in the synthesis of following:
- benzothiazole
- 4-methoxybenzothioamide
- 2-(4-methoxyphenyl)imidazoline
- 7-chloro-4′-methoxythioflavone
signalword
Danger
hcodes
Storage Class
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
flash_point_f
194.0 °F - closed cup
flash_point_c
90 °C - closed cup
Hazard Classifications
Acute Tox. 3 Oral - Aquatic Acute 1 - Eye Dam. 1 - Skin Corr. 1B
Regulatory Information
监管及禁止进口产品
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Mehdi Bakavoli et al.
Molecules (Basel, Switzerland), 14(12), 4849-4857 (2009-12-25)
Cyclocondensation of 2-[bis(methylthio)methylene]malononitrile (1) and cysteamine (2) afforded 2-(thiazolidin-2-ylidene)malononitrile (3). This compound on treatment with NaSH gave the corresponding thioamide derivative 4a in a regioselective manner on the basis of its single crystal X-ray diffraction analysis. Reaction of this compound
Bruna M Santos et al.
Acta physiologica (Oxford, England), 228(3), e13373-e13373 (2019-09-05)
Whereas some patients have important changes in body core temperature (Tb) during systemic inflammation, others maintain a normal Tb, which is intrinsically associated to immune paralysis. One classical model to study immune paralysis is the use of repeated administration of
Synthesis of Benzothiazoles through Copper-Catalyzed One-Pot Three-Component Reactions with Use of Sodium Hydrosulfide as a Sulfur Surrogate.
Park N, et al.
European Journal of Organic Chemistry, 10, 1984-1993 (2012)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 161527-5G | 04061838746481 |
| 161527-100G | 04061838746450 |
| 161527-3KG | 04061838746474 |
| 161527-1KG | 04061838746467 |