Skip to Content
Merck
CN
All Photos(5)

Documents

156264

Sigma-Aldrich

Ammonium formate

reagent grade, 97%

Synonym(s):

Formic acid ammonium salt

Sign Into View Organizational & Contract Pricing
All Photos(5)

About This Item

Linear Formula:
HCO2NH4
CAS Number:
540-69-2
Molecular Weight:
63.06
Beilstein:
3625095
EC Number:
208-753-9
MDL number:
MFCD00013103
UNSPSC Code:
12352106
eCl@ss:
39021903
PubChem Substance ID:
329750948
NACRES:
NA.21

grade

reagent grade

Quality Level

100

Assay

97%

form

granular
moist crystals

pH

5.5-7.5 (25 °C, 63.1 g/L)

mp

119-121 °C (lit.)

density

1.26 g/mL at 25 °C (lit.)

SMILES string

N.OC=O

InChI

1S/CH2O2.H3N/c2-1-3;/h1H,(H,2,3);1H3

InChI key

VZTDIZULWFCMLS-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

General description

Ammonium formate is an ammonium salt of formic acid. It is a cheap and promising N-formylating agent for various amines (secondary and aniline). Its anhydrous form may be employed as a catalyst for the synthesis of various amino derivatives from aliphatic and aromatic compounds.
Ammonium formate can be used as a source to produce ammonia. It can also be used in the reductive alkylation of amines.

Application

Ammonium formate may be employed in the following studies:
  • Deprotection of N-benzyl derivatives of amino acids and amines to afford free amino acids and amines.
  • Conversion of α, β-unsaturated nitroalkenes to the corresponding oximes.
  • Preparation of nitriles.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H319

Hazard Classifications

Eye Irrit. 2

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Appukkuttan P et al.
Microwave Methods in Organic Synthesis, 266 (2006)
Trost.MB
Comprehensive Organic Synthesis, 8 (1991)
Copper-Catalyzed Synthesis of Nitriles by Aerobic Oxidative Reaction of Alcohols and Ammonium Formate.
Yadav DKT and Bhanage BM.
European Journal of Organic Chemistry, 23, 5106-5110 (2013)
Rapid debenzylation of N-benzylamino derivatives to amino-derivatives using ammonium formate as catalytic hydrogen transfer agent.
Ram S and Spicer LD.
Tetrahedron Letters, 28(5), 515-516 (1987)
The palladium assisted transfer reduction of a, ?-unsaturated nitroalkenes to oximes using ammonium formate.
Kabalka GW, et al.
Synthetic Communications, 20(16), 2453-2458 (1990)
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service