156264
Ammonium formate
reagent grade, 97%
Synonym(s):
Formic acid ammonium salt
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About This Item
Linear Formula:
HCO2NH4
CAS Number:
Molecular Weight:
63.06
Beilstein:
3625095
EC Number:
MDL number:
UNSPSC Code:
12352106
eCl@ss:
39021903
PubChem Substance ID:
NACRES:
NA.21
Assay:
97%
grade:
reagent grade
form:
granular
moist crystals
moist crystals
Recommended Products
grade
reagent grade
Quality Level
Assay
97%
form
granular
moist crystals
pH
5.5-7.5 (25 °C, 63.1 g/L)
mp
119-121 °C (lit.)
density
1.26 g/mL at 25 °C (lit.)
SMILES string
N.OC=O
InChI
1S/CH2O2.H3N/c2-1-3;/h1H,(H,2,3);1H3
InChI key
VZTDIZULWFCMLS-UHFFFAOYSA-N
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General description
Ammonium formate is an ammonium salt of formic acid. It is a cheap and promising N-formylating agent for various amines (secondary and aniline). Its anhydrous form may be employed as a catalyst for the synthesis of various amino derivatives from aliphatic and aromatic compounds.
Ammonium formate can be used as a source to produce ammonia. It can also be used in the reductive alkylation of amines.
Ammonium formate can be used as a source to produce ammonia. It can also be used in the reductive alkylation of amines.
Application
Ammonium formate may be employed in the following studies:
- Deprotection of N-benzyl derivatives of amino acids and amines to afford free amino acids and amines.
- Conversion of α, β-unsaturated nitroalkenes to the corresponding oximes.
- Preparation of nitriles.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Trost.MB
Comprehensive Organic Synthesis, 8 (1991)
Copper-Catalyzed Synthesis of Nitriles by Aerobic Oxidative Reaction of Alcohols and Ammonium Formate.
Yadav DKT and Bhanage BM.
European Journal of Organic Chemistry, 23, 5106-5110 (2013)
Appukkuttan P et al.
Microwave Methods in Organic Synthesis, 266 (2006)
The palladium assisted transfer reduction of a, ?-unsaturated nitroalkenes to oximes using ammonium formate.
Kabalka GW, et al.
Synthetic Communications, 20(16), 2453-2458 (1990)
A convenient method for the N-formylation of secondary amines and anilines using ammonium formate.
Reddy PG, et al.
Tetrahedron Letters, 41(47), 9149-9151 (2000)
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