12902
Potassium hexacyanocobaltate(III)
≥97.0%
Synonym(s):
Tripotassium hexacyanocobaltate(III)
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About This Item
Linear Formula:
K3Co(CN)6
CAS Number:
Molecular Weight:
332.33
NACRES:
NA.55
PubChem Substance ID:
UNSPSC Code:
12352202
EC Number:
237-742-1
MDL number:
Assay:
≥97.0%
Form:
crystalline
InChI key
VSUFNKULKBVQQW-UHFFFAOYSA-N
InChI
1S/6CN.Co.3K/c6*1-2;;;;/q;;;;;;-3;3*+1
SMILES string
[K+].[K+].[K+].N#C[Co-3](C#N)(C#N)(C#N)(C#N)C#N
assay
≥97.0%
form
crystalline
reaction suitability
reagent type: catalyst
core: cobalt
impurities
≤0.1% free cyanide
density
1.878 g/mL at 25 °C (lit.)
anion traces
sulfate (SO42-): ≤500 mg/kg
cation traces
Fe: ≤50 mg/kg
suitability
suitable for acidity or alkalinity (alkalinity <= 0.15 meq/g)
Quality Level
Related Categories
Application
Potassiumhexacyanocobaltate(III) can be used as a complexing agent to synthesize double metal cyanide catalyst:
- For the chemoselective reductive amination of carbonyl compounds with aromatic amines to synthesize substituted amines in the presence of polymethylhydrosiloxane as a reducing agent.
- In the ring opening polymerization of propylene oxide to synthesize polyols.
- In the coupling reaction of CO2 with hydrous epoxides to synthesize cyclic carbonates.
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Edward E Little et al.
Environmental science and pollution research international, 14(5), 333-337 (2007-08-29)
Cobalt cyanide complexes often result when ore is treated with cyanide solutions to extract gold and other metals. These have recently been discovered in low but significant concentrations in effluents from gold leach operations. This study was conducted to determine
Effect of pH on Retention of 134Cs and 60Co from MAW by Potassium Hexacyanocobaltate(III).
Mekhail FM, et al.
Isotopes in Environmental and Health Studies, 130-133 (1991)
A 59Co NMR relaxation probe of macromolecule anionic binding sites.
T Raj et al.
Analytical biochemistry, 106(2), 373-376 (1980-08-01)
Samir Fernando Castilla-Acevedo et al.
Journal of hazardous materials, 392, 122389-122389 (2020-03-17)
The ultraviolet light activation of persulfate (PS) was evaluated for the degradation of cobalt cyanocomplexes, which are considered as some of the most recalcitrant compounds present in mining wastewater. The influence of the solution pH (11 and 13), initial concentration
Xin Zhang et al.
ChemSusChem, 14(1), 467-478 (2020-10-13)
Electrolytic water splitting using surplus electricity represents one of the most cost-effective and promising strategies for hydrogen production. The high overpotential of the oxygen-evolution reaction (OER) caused by the multi-electron transfer process with a high chemical energy barrier, however, limits
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